Metal–organic frameworks (MOFs) are widely used in environmental remediation due to their unique properties. However, their practical applications are significantly limited by its powder crystal form. To address these limitations, MOFs can be integrated with abundant and sustainable biomass‐derived nanocellulose (NC) to construct processable macroscopic architectures. Herein, this review discusses recent advances in the preparation of multi‐dimensional macroscopic materials from MOFs‐NC and their applications in environmental remediation, including dye adsorption and degradation, pharmaceutical removal, heavy metal ion capture, adsorption and degradation of volatile organic compounds (VOCs), CO ₂ capture and separation, particulate matter (PM) separation, and others. A summary of two commonly used strategies for preparing MOFs‐NC composites proposes a valuable insight on how processable macroscopic architectures can be effectively achieved. Furthermore, this review provides an overview of the structure‐property‐function relationship between multi‐dimensional MOFs‐NC composites and highlights their versatile applications in the remediation of polluted environments. The mechanisms, challenges, and future prospects of the material in removing environmental pollutants are also present in detail. This review aims to guide researchers in designing high‐performance, multi‐functional, sustainable, and scalable MOFs‐NC composites for future environmental remediation.

Studies on the influence of drying processes on cellulose nanofiber (CNF) aerogel performance has always been a great challenge. In this study, CNF aerogels were prepared via two different drying techniques. The CNF solution was prepared via existing chemical methods, and the resultant aerogel was fabricated through supercritical CO₂ drying and liquid nitrogen freeze-drying techniques. The microstructure, shrinkage, specific surface area, pore volume, density, compression strength, and isothermal desorption curves of CNF aerogel were characterized. The aerogel obtained from the liquid nitrogen freeze-drying method showed a relatively higher shrinkage, higher compression strength, lower specific surface area, higher pore volume, and higher density. The N₂ adsorption capacity and pore diameter of the aerogel obtained via the liquid nitrogen freeze-drying method were lower than the aerogel that underwent supercritical CO₂ drying. However, the structures of CNF aerogels obtained from these two drying methods were extremely similar.