As natural gas-fired combined cycle (NGCC) power plants continue to constitute a crucial part of the global energy landscape, their carbon dioxide (CO2) emissions pose a significant challenge to climate goals. This paper evaluates the feasibility of implementing post-combustion carbon capture, storage, and utilization (CCSU) technologies in NGCC power plants for end-of-pipe decarbonization in Uzbekistan. This study simulates and models a 450 MW NGCC power plant block, a first-generation, technically proven solvent—MEA-based CO2 absorption plant—and CO2 compression and pipeline transportation to nearby oil reservoirs to evaluate the technical, economic, and environmental aspects of CCSU integration. Parametric sensitivity analysis is employed to minimize energy consumption in the regeneration process. The economic analysis evaluates the levelized cost of electricity (LCOE) on the basis of capital expenses (CAPEX) and operational expenses (OPEX). The results indicate that CCSU integration can significantly reduce CO2 emissions by more than 1.05 million tonnes annually at a 90% capture rate, although it impacts plant efficiency, which decreases from 55.8% to 46.8% because of the significant amount of low-pressure steam extraction for solvent regeneration at 3.97 GJ/tonne CO2 and multi-stage CO2 compression for pipeline transportation and subsequent storage. Moreover, the CO2 capture, compression, and transportation costs are almost 61 USD per tonne, with an equivalent LCOE increase of approximately 45% from the base case. This paper concludes that while CCSU integration offers a promising path for the decarbonization of NGCC plants in Uzbekistan in the near- and mid-term, its implementation requires massive investments due to the large scale of these plants.
Optimal steam process drive sizing is crucial for efficient and sustainable operation of energy-intense industries. Recent years have brought several methods assessing this problem, which differ in complexity and user-friendliness. In this paper, a novel complex method was developed and presented and its superiority over other approaches was documented on an industrial case study. Both the process-side and steam-side characteristics were analyzed to obtain correct model input data: Driven equipment performance and efficiency maps were considered, off-design and seasonal operation was studied, and steam network topology was included. Operational data processing and sizing calculations were performed in a linked MATLAB®–Aspen Plus® environment, exploiting the strong sides of both software tools. The case study aimed to replace a condensing steam turbine by a backpressure one, revealing that: 1. Simpler methods neglecting frictional pressure losses and off-design turbine operation efficiency loss undersized the drive and led to unacceptable loss of deliverable power to the process; 2. the associated process production loss amounted up to 20%; 3. existing bottlenecks in refinery steam pipelines operation were removed; however, new ones were created; and 4. the effect on the marginal steam source operation may vary seasonally. These findings accentuate the value and viability of the presented method.
25 May 2024 in Chemical Engineering Research and Design
Steam crackers (ethylene plants) belong to the most complex industrial plants and offer significant potential for energy-saving translated into the reduction of greenhouse gas emissions. Steam export to or import from adjacent units or complexes can boost the associated financial benefit, but its energy and environmental impact are questionable. A study was carried out on a medium-capacity ethylene plant using field data to: 1. Estimate the energy savings potential achievable by optimizing internal steam management and optimizing steam export/import; 2. Quantify the associated change in air pollutant emissions; 3. Analyze the impact of the increasing carbon price on the measures adopted. Internal steam management optimization yielded steam let-down rate minimization and resulted in a 5% (87 TJ/year) reduction in steam cracker’s steam boiler fuel consumption and the associated cut of CO2 emissions by almost 4900 t/year and that of NOx emissions by more than 5 t/year. Steam import to the ethylene plant from the refinery proved to be purely economic-driven, as it increased the net fuel consumption of the ethylene plant and the refinery complex by 12 TJ/year and resulted in an increase of net emissions of nearly all considered air pollutants (more than 7000 t/year of CO2, over 15 t/year of NOx, over 18 t/year of SOx) except for CO, where the net change was almost zero. The effect of external emissions change due to the associated backpressure electricity production surplus (over 11 GWh/year) was too low to compensate for this increase unless fossil fuel-based electricity production was considered. The increase of carbon price impact on the internal steam management optimization economics was favorable, while a switch to steam export from the ethylene plant, instead of steam import, might be feasible if the carbon price increased to over 100 €/tCO2.