Heavy metal (HM) contamination poses a major threat to environmental health, agriculture and human well-being, requiring effective and sustainable remediation strategies. Phytoremediation, an eco-friendly and cost-effective approach, is widely used for the remediation of HM-contaminated soils. Although phytoremediation holds considerable potential in the extraction, stabilisation and degradation of HMs, its effectiveness is often constrained by limited metal bioavailability, plant stress under toxic conditions and slow metal uptake rates. To address these limitations, this review examines the integration of various soil amendments—the application of biochar, compost, plant exudates, microbial agents and chelating agents—to enhance phytoremediation efficiency. This review critically evaluates empirical evidence on the effectiveness, scalability, economic feasibility and environmental impact of these amendments. By synthesising recent studies, this review advances the understanding of amendment-assisted phytoremediation as a viable solution for treating HM-contaminated soils. In addition, this review identifies practical applications, discusses limitations and explores the potential synergies of these amendments to optimise phytoremediation strategies, ultimately contributing to more effective and sustainable environmental cleanup efforts.

Various applications of superabsorbent polymers (SAP) include the use of these materials in agriculture and environmental engineering to increase soil water retention. Under such conditions, there is water absorption of the SAP in soil under load. This paper presents the results of absorbency under load (AUL) of a cross-linked copolymer of acrylamide and potassium acrylate mixed at ratios of 0.3%, 0.5% and 1.0% with coarse sand and sandy loam. The mixtures were subjected to loads equivalent to 10, 20 and 40 cm of soil. The highest differences in AUL values for both soils, compared to the control sample, were obtained after 24 hours and at a maximum load of 5.9 kPa, which corresponds to a load of a 40 cm thick topsoil layer. The AUL was 71.4 g∙g⁻¹ for coarse sand and 52.7 g∙g⁻¹ for sandy loam with a 1.0% SAP addition, which corresponded to 24.0% and 18.0%, respectively, of the absorption in the control sample. All the conducted tests revealed a significantly low rate of water absorbency, which is especially important for capturing the water that infiltrates into the soil profile. The results demonstrate that water absorption by SAPs decreased with the increase in SAP addition.

Water uptake dynamics of superabsorbent polymers (SAP) in soil is of key importance for the optimum application of these materials in environmental engineering and agriculture, so goal of this paper is to determine time dependent values of coefficient of permeability for various SAP-soil mixtures. Retaining water in soil is a key requirement in critical zones to support plant growth. There is an urgent need for technologies that can increase soil water retention, given the increasing prevalence of droughts and scarcity of clean water as the climate changes, combined with the rising demand for food by a growing world population. SAPs are materials that can absorb significant amounts of water, and thus have tremendous potential to help increase water retention in soil. However, while some studies have characterized the equilibrium swelling behavior of SAPs in soil, how their addition influences the time-dependent flow of water through soil remains poorly understood. Here, we address this gap in knowledge by directly measuring the coefficient of permeability of SAP-soil mixtures, testing different soil grain sizes, SAP grain sizes, and different SAP-soil ratios. We find that SAP addition can dramatically hinder the flow rate of water through soil—reducing the permeability by several orders of magnitude, and in some cases causing complete blockage of water infiltration, at mass fractions as small as 1%. In this scenario coefficient of permeability of 1.23 × 10⁻⁴ m/s dropped by a factor of ~10 after 14 min, a factor of ~100 after 36 min, and by nearly a factor of ~1000 after 63 min, eventually causing complete blockage of infiltration after 67 min. Authors concluded that in this particular situation the size and quantity of SAP particles was enough to nearly completely fill the available pore space resulting in rendering the soil column almost completely impermeable. Moreover, we demonstrate that these effects are well-described by a simple hydraulic model of the mutual interactions between SAP and soil grains, providing more generally-applicable and quantitative principles to model SAP-soil permeability in applications. Ultimately, this work could help evaluate the optimal proportions and grain sizes of SAPs to use for a given soil to simultaneously achieve a desirable permeability along with increased water holding capacity in the plant root zone.

Superabsorbent polymers (SAPs) are used in agriculture and environmental engineering to increase soil water retention. Under such conditions, the swelling pressure of the SAP in soil affects water absorption by SAP, and soil structure. The paper presents the results of swelling pressure of three cross-linked copolymers of acrylamide and potassium acrylate mixed at the ratios of 0.3%, 0.5% and 1.0% with coarse sand and loamy sand. The highest values of swelling pressure were obtained for the 1% proportion, for coarse sand (79.53 kPa) and loamy sand (78.23 kPa). The time required to reach 90% of swelling pressure for each type of SAP differs. Samples of coarse sand mixed with SAP K2 in all concentrations reached 90% of total swelling pressure in 100 min, while the loamy sand mixtures needed only about 60 min. The results were the basis for developing a model for swelling pressure of the superabsorbent and soil mixtures, which is a fully stochastic model. The conducted research demonstrated that the course of pressure increase depends on the available pore capacity and the grain size distribution of SAPs. The obtained results and the proposed model may be applied everywhere where mixtures of SAPs and soils are used to improve plant vegetation conditions.