Ordos Basin is an important continental shale gas exploration site in China. The micropore structure of the shale reservoir is of great importance for shale gas evaluation. The Taiyuan Formation of the lower Permian is the main exploration interval for this area. To examine the nanometer pore structures in the Taiyuan Formation shale reservoirs in the Lin-Xing area, Northern Shaanxi, the microscopic pore structure characteristics were analyzed via nitrogen adsorption experiments. The pore structure parameters, such as specific surface area, pore volume, and aperture distribution, of shale were calculated; the significance of the pore structure for shale gas storage was analyzed; and the main controlling factors of pore development were assessed. The results indicated the surface area and hole volume of the shale sample to be 0.141–2.188 m²/g and 0.001398–0.008718 cm³/g, respectively. According to the IUPAC (International Union of Pure and Applied Chemistry) classification, mesopores and macropores were dominant in the pore structure, with the presence of a certain number of micropores. The adsorption curves were similar to the standard IV (a)-type isotherm line, and the hysteresis loop type was mainly similar to H3 and H4 types, indicating that most pores are dominated by open type pores, such as parallel plate-shaped pores and wedge-shaped slit pores. The micropores and mesopores provide the vast majority of the specific surface area, functioning as the main area for the adsorption of gas in the shale. The mesopores and macropores provide the vast majority of the pore volume, functioning as the main storage areas for the gas in the shale. Total organic carbon had no notable linear correlation with the total pore volume and the specific surface area. Vitrinite reflectance (Ro) had no notable correlation with the specific surface area, but did have a low “U” curve correlation with the total pore volume. There was no relationship between the quartz content and specific surface area and total pore volume. In addition, there was no notable correlation between the clay mineral content and total specific surface area and total pore volume.

There are enormous resources of unconventional gas in coal measures in Ordos Basin. In order to study the geological characteristics of unconventional gas in coal Measures in Ordos Basin, we analyzed and summarized the results of previous studies. Analysis results are found that, the unconventional gas in coal measures is mainly developed in Upper Paleozoic in Eastern Ordos Basin, which including coalbed methane, shale gas and tight sandstone gas. The oil and gas show active in coal, shale and tight sandstone of Upper Paleozoic in Ordos Basin. Coalbed methane reservoir and shale gas reservoir in coal measures belong to “self-generation and self- preservation”, whereas the coal measures tight sandstone gas reservoir belongs to “allogenic and self-preservation”. The forming factors of the three different kinds of gasses reservoir are closely related and uniform. We have the concluded that it will be more scientific and reasonable that the geological reservoir-forming processes of three different kinds of unconventional gas of coal measures are studied as a whole in Ordos Basin, and at a later stage, the research on joint exploration and co-mining for the three types of gasses ought to be carried out.