Carbon-based nanomaterials (CBM) have shown great potential for various environmental applications because of their physical and chemical properties. The unique hybridization properties of CBMs allow for the tailored manipulation of their structures and morphologies. However, owing to poor solar light absorption, and the rapid recombination of photogenerated electron-hole pairs, pristine carbon materials typically have unsatisfactory photocatalytic performances and practical applications. The main challenge in this field is the design of economical, environmentally friendly, and effective photocatalysts. Combining carbonaceous materials with carbonaceous semiconductors of different structures results in unique properties in carbon-based catalysts, which offers a promising approach to achieving efficient application. Here, we review the contribution of CBMs with different dimensions, to the catalytic removal of organic pollutants from wastewater by catalyzing the Fenton reaction and photocatalytic processes. This review, therefore, aims to provide an appropriate direction for empowering improvements in ongoing research work, which will boost future applications and contribute to overcoming the existing limitations in this field.
Blood-contacting devices must be designed to minimize the risk of bloodstream-associated infections, thrombosis, and intimal lesions caused by surface friction. However, achieving effective prevention of both bloodstream-associated infections and thrombosis poses a challenge due to the conflicting nature of antibacterial and antithrombotic activities, specifically regarding electrostatic interactions. This study introduced a novel biocompatible hydrogel of sodium alginate and zwitterionic carboxymethyl chitosan (ZW@CMC) with antibacterial and antithrombotic activities for use in catheters. The ZW@CMC hydrogel demonstrates a superhydrophilic surface and good hygroscopic properties, which facilitate the formation of a stable hydration layer with low friction. The zwitterionic-functionalized CMC incorporates an additional negative sulfone group and increased negative charge density in the carboxyl group. This augmentation enhances electrostatic repulsion and facilitates the formation of hydration layer. This leads to exceptional prevention of blood clotting factor adhesion and inhibition of biofilm formation. Subsequently, the ZW@CMC hydrogel exhibited biocompatibility with tests of in vitro cytotoxicity, hemolysis, and catheter friction. Furthermore, in vivo tests of antithrombotic and systemic inflammation models with catheterization indicated that ZW@CMC has significant advantages for practical applications in cardiovascular-related and sepsis treatment. This study opens a new avenue for the development of chitosan-based multifunctional hydrogel for applications in blood-contacting devices.
A carbon fiber reinforced thermoplastic (CFRTP) was irradiated with a high energy electron-beam. As a result, the tensile strength of high-density polyethylene (HDPE)-based CFRTPs was significantly improved by gradually increasing the electron-beam dose. It was confirmed that the adhesion between CF and HDPE was improved and the surface properties of CF and HDPE were readily modified by electron-beam. It was verified from spectroscopic analysis that various oxygen-containing functional groups were formed on the surface of CF and HDPE by irradiation and we believe that strong attractive interactions took place among these functional groups at the interface of CFs and HDPE. Finally, it was conclusive that electron-beam irradiation provided two main effects on CFRTPs. One was cross-linking of thermoplastic resin for efficient load transfer from resin to CF and the other was formation of surface functional group and attractive interaction of these functional groups at the interface of fiber and matrix. These two effects showed synergetic contribution to enhance the mechanical properties of CFRTP.