A shock wave that is characterized by sharp physical gradients always draws the medium out of equilibrium. In this work, both hydrodynamic and thermodynamic nonequilibrium effects around the shock wave are investigated using a discrete Boltzmann model. Via Chapman–Enskog analysis, the local equilibrium and nonequilibrium velocity distribution functions in one-, two-, and three-dimensional velocity space are recovered across the shock wave. Besides, the absolute and relative deviation degrees are defined in order to describe the departure of the fluid system from the equilibrium state. The local and global nonequilibrium effects, nonorganized energy, and nonorganized energy flux are also investigated. Moreover, the impacts of the relaxation frequency, Mach number, thermal conductivity, viscosity, and the specific heat ratio on the nonequilibrium behaviours around shock waves are studied. This work is helpful for a deeper understanding of the fine structures of shock wave and nonequilibrium statistical mechanics.

In this work, a central-moment-based discrete Boltzmann method (CDBM) is constructed for fluid flows with variable specific heat ratios. The central kinetic moments are employed to calculate the equilibrium discrete velocity distribution function in the CDBM. In comparison to previous incompressible central-moment-based lattice Boltzmann method, the CDBM possesses the capability of investigating compressible flows with thermodynamic nonequilibrium effects beyond conventional hydrodynamic models. Unlike all existing DBMs which are constructed in raw-moment space, the CDBM stands out by directly providing the nonequilibrium effects related to the thermal fluctuation. The proposed method has been rigorously validated using benchmarks of the Sod shock tube, Lax shock tube, shock wave phenomena, two-dimensional sound wave, and the Taylor-Green vortex flow. The numerical results exhibit an exceptional agreement with theoretical predictions.