Constructed wetlands (CWs) are eco-technologies used for wastewater treatment, where vegetation is a key component. In recent decades, the adaptability and phytoremediation functions of ornamental plants (OPs)—which are not typically found in natural wetlands—have been tested. However, few comprehensive studies address the processes or mechanisms by which these OPs enhance pollutant removal in CWs and their artisanal applications. It is also vital to understand the most used OP species in CWs and their advantages in phytoremediation. Thus, this study enhances the understanding of the processes involved in pollutant degradation within CWs, specifically focusing on absorption, adsorption, translocation, radial oxygen loss, and root exudates. It reaffirms the essential role that plants play in these systems, as suggested in previous scientific reports, and discusses some potential applications for the ornamental plants produced in CWs, such as flower arrangements and crafts. This also includes the social aspect, emphasizing community engagement through social capital initiatives for the adoption and appropriation of the ecotechnology. Additionally, a bibliometric analysis revealed that Mexico is among the countries with the most significant research on OPs in CWs, particularly concerning commercially valuable species, followed by India and China. These findings can be instrumental in planning future community projects focused on wastewater treatment using CWs using OPs.