The aim of this study was to investigate the properties of an organic binder used in cold-bonded briquettes (CBBs) prepared from two different iron bearing materials. The applied binder is a type of starch as indicated by chemical analysis, iodine-starch staining and Fourier transform infrared analyses. Thermogravimetric differential scanning calorimetry showed that the binder pyrolysis undergoes four stages: moisture desorption, ash volatilization, pyrolysis of organic matter and decomposition of materials with high activation energy. The difference between the dry and heat-treated samples during the macroscopic failure process is the instability propagation of the crack. The CBB shows a low decrepitation index at 700 °C. The returned fines of CBBs used with the organic binder were applied in two blast furnaces. The industrial trials showed that the CBBs do not influence the performance of the blast furnace and can reduce the fuel consumption rate. The curing rate of the binder decreases, and the growth rate of compressive strength decreases during the curing process. Iron ore particles are bonded together and exist in the form of aggregation after mixing with water and binder. The edges and corners of the particles become blurred, and the original surfaces of the particles are covered with binder film, the surface of which is covered with fine particles. The multi-branched structure of amylopectin provides omnibearing adhesion sites, thus forming binder agglomeration and film leading to a strong adhesion between binder and iron ore particles. Binder film and binder agglomeration work together to make the CBB perform well.

The advancement of metallurgical vessels, such as blast furnaces, shaft furnaces, and torpedo ladles, can be better controlled and expanded for a greater lifespan if the thickness of the refractory lining wear is known and predicted. In the past, various methods including radioactive tracers, infrared (IR) thermography, electromagnetic waves, ultrasonic tomography, and temperature field have been tested to determine the thickness of the refractory wall. However, for various reasons, these methods have failed to be effective. This paper presents a novel method—electromotive force (EMF)—for predicting the thickness of refractory lining wear in vessels, including a small-scale vessel in the laboratory, an industrial torpedo ladle, and in the two refining hearths of blast furnaces. The experimental results show that the magnitude of the EMF signal increases with a decrease in wall thickness. Prediction values of the refractory wall thickness are consistent with measured ones. The relative error of EMF measurement for the torpedo ladle is around 6.8%. The EMF measurement of blast furnace hearths is quite accurate, and the relative error is less than 11%.