Hollow fibre membrane contactor (HFMC) systems have been studied for the desorption of dissolved methane from both analogue and real anaerobic effluents to ascertain process boundary conditions for separation. When using analogue effluents to establish baseline conditions, up to 98.9% methane removal was demonstrated. Elevated organic concentrations have been previously shown to promote micropore wetting. Consequently, for anaerobic effluent from an upflow anaerobic sludge blanket reactor, which was characterised by a high organic concentration, a nonporous HFMC was selected. Interestingly, mass transfer data from real effluent exceeded that produced with the analogue effluent and was ostensibly due to methane supersaturation of the anaerobic effluent which increased the concentration gradient yielding enhanced mass transfer. However, at high liquid velocities a palpable decline in removal efficiency was noted for the nonporous HFMC which was ascribed to the low permeability of the nonporous polymer provoking membrane controlled mass transfer. For anaerobic effluent from an anaerobic membrane bioreactor (MBR), a microporous HFMC was used as the permeate comprised only a low organic solute concentration. Mass transfer data compared similarly to that of an analogue which suggests that the low organic concentration in anaerobic MBR permeate does not promote pore wetting in microporous HFMC. Importantly, scale-up modelling of the mass transfer data evidenced that whilst dissolved methane is in dilute form, the revenue generated from the recovered methane is sufficient to offset operational and investment costs of a single stage recovery process, however, the economic return is diminished if discharge is to a closed conduit as this requires a multi-stage array to achieve the required dissolved methane consent of 0.14mgl−1

This paper demonstrates the potential for recovering dissolved methane from low temperature anaerobic processes treating domestic wastewater. In the absence of methane recovery, ca. 45% of the produced methane is released as a fugitive emission which results in a net carbon footprint of −0.47 kg CO_2e m⁻³. A poly-di-methyl-siloxane (PDMS) membrane contactor was applied to support sweep gas desorption of dissolved methane using nitrogen. The dense membrane structure controlled gaseous mass transfer thus recovery was maximised at low liquid velocities. At the lowest liquid velocity, V_L, of 0.0025 m s⁻¹, 72% of the dissolved methane was recovered. A vacuum was also trialled as an alternative to sweep-gas operation. At vacuum pressures below 30 mbar, reasonable methane recovery was observed at an intermediate V_L of 0.0056 m s⁻¹. Results from this study demonstrate that dissolved methane recovery could increase net electrical production from low temperature anaerobic processes by ca. +0.043 kWh_e m⁻³ and reduce the net carbon footprint to +0.01 kg CO_2e m⁻³. However, further experimental work to optimise the gas-side hydrodynamics is required as well as validation of the long-term impacts of biofouling on process performance.