In the packaging industry, the barrier property of packaging materials is of paramount importance. The enhancement of barrier properties of materials can be achieved by adding impermeable nanoparticles into thin polymeric films, known as mixed-matrix membranes (MMMs). Three-dimensional numerical simulations were performed to study the barrier property of these MMMs and to estimate the effective membrane gas permeability. Results show that horizontally-aligned thin cuboid nanoparticles offer far superior barrier properties than spherical nanoparticles for an identical solid volume fraction. Maxwell’s model predicts very well the relative permeability of spherical and cubic nanoparticles over a wide range of the solid volume fraction. However, Maxwell’s model shows an increasingly poor prediction of the relative permeability of MMM as the aspect ratio of cuboid nanoparticles tends to zero or infinity. An artificial neural network (ANN) model was developed successfully to predict the relative permeability of MMMs as a function of the relative thickness and the relative projected area of the embedded nanoparticles. However, since an ANN model does not provide an explicit form of the relation of the relative permeability with the physical characteristics of the MMM, a new model based on multivariable regression analysis is introduced to represent the relative permeability in a MMM with impermeable cuboid nanoparticles. The new model possesses a simple explicit form and can predict, very well, the relative permeability over an extensive range of the solid volume fraction and aspect ratio, compared with many existing models.
Applying solar collectors is a popular tool for harnessing solar energy. In this work, a flat plate solar air collector was investigated under direct solar radiation in an endeavor to enhance the thermal efficiency of solar air collector with a slatted glass cover, perforated absorber aluminum sheets (porosity 0.0177, 0.0314 and absorber thickness of 1.25, 2.5 mm) which is the most suitable for a solar dryer. The effects of porosity and thickness on absorber performance of collector were evaluated. Six levels of air mass flow rates (0.0056 to 0.0385 kg m−2 s−1) were adopted. The tests were conducted in three replications on very clear sky days in September and October. The experimental results showed that thermal efficiency of collector was increased by an increase in the porosity of the absorber. The absorber with lower porosity showed a better thermal efficiency at lower air mass flux. In the minimum air flow rate, absorber efficiency with porosity 0.0177 and 0.0314 was 0.31 and 0.29, respectively, whereas at the maximum flow, efficiency showed an enormous change of 0.83 and 0.88, respectively. This solar air heater can be used for drying agricultural products, heating the space of greenhouse, and so forth.