All light or heavy water reactors fabricated with carbon steels suffer from flow-accelerated corrosion (FAC). The FAC degradation of SA106B with different flow velocities was investigated in terms of microstructure. As flow velocity increased, the major corrosion type changed from general corrosion to localized corrosion. Severe localized corrosion occurred in the pearlite zone, which can be the prior location for generating pits. After normalizing, the improvement in microstructure homogeneity reduced the oxidation kinetics and lowered cracking sensitivity, causing a decrease in FAC rates of 33.28%, 22.47%, 22.15%, and 17.53% at flow velocity of 0 m/s, 1.63 m/s, 2.99 m/s, and 4.34 m/s, respectively. Additionally, localized corrosion tendency was decreased by reducing the micro-galvanic effect and tensile stresses in oxide film. The maximum localized corrosion rate decreased by 21.7%, 13.5%, 13.8%, and 25.4% at flow velocity of 0 m/s, 1.63 m/s, 2.99 m/s, and 4.34 m/s, respectively.

The microstructural evolution and mechanical behavior of cast duplex stainless steels (CDSSs) at 400 °C for different thermal aging times were investigated by transmission electron microscope (TEM) and small punch test (SPT). The results showed that the spinodal decomposition in ferrite was the main reason for the decrease in toughness, and G-phase did not play an important role in the embrittlement process. The change of membrane stretching zone (W_m) played an important role in the SPT load-displacement curve before and after thermal aging. During the deformation process of W_m in the SPT, for thermal aging for 10,000 h, some completely curved slip bands were generated inside the ferrite phase, which had no contact with the δ/γ phase interface and belonged to the slip bands produced by the independent deformation of ferrite. The combined effect of the curved slip bands and stress concentration led to the initiation of obvious micro-cracks at the δ/γ phase interface. The micro-cracks propagated along the ferrite phase curved slip bands, and eventually penetrated the entire hardened ferrite phase.

The corrosion behavior of oilfield used L245N standard steel was tested in simulated oilfield solution by dynamic high-temperature autoclave. The corrosion products were characterized by using scanning electron microscopy (SEM), X-ray diffraction (XRD) and Electrochemical impedance spectroscopy (EIS) respectively. In addition, the corrosion rates and surface morphological characteristics of the steels after different exposure times were studied. The results showed that the corrosion rate decreased sharply and then increased with time in the high salinity flow solution, which was related to the formation of corrosion scale and the remaining cementite within it. At the beginning of the exposure time, the formed corrosion scale became thicker, resulting in a significant decrease of the corrosion rate. While with increasing time, on the one hand, the increased remaining cementite within corrosion scale facilitated the corrosion by the galvanic corrosion between the remaining cementite and the ferrite within the metal. On the other hand, the protective effect of corrosion scale formed on the remaining cementite skeleton declined due to the formation of large amounts of Fe_xCa_1−xCO₃, which also promoted the corrosion rate of the steels, both these ways contributed to a slow increase of corrosion rate.

Q355 carbon steel was exposed for 0.5 and 1 year in Pingtan Strait to examine how surface-wetness changes affect early rust-layer evolution and localized corrosion. Environmental monitoring, corrosion-rate measurements, rust-phase analysis, and electrochemical characterization were combined to characterize corrosion in this humid, salt-laden marine atmosphere. The exposure regime shifted from sustained wetness during the first half-year to frequent wet–dry cycling during the second. Although the average corrosion rate remained nearly unchanged, localized corrosion intensified and adjacent pits became interconnected. This change was closely associated with the evolution of the rust-phase assemblage and its spatial distribution. After 0.5 years, β-FeOOH was dominant, consistent with a long time of wetness (TOW) and Cl⁻ enrichment in surface electrolyte films, and pits remained largely isolated. After 1 year, Fe₃O₄ increased substantially and became the dominant phase, possibly because frequent wet–dry cycling altered oxygen transport within the rust and repeatedly produced locally oxygen-deficient conditions. Fe₃O₄ enrichment promoted continued pit deepening, followed by pit expansion and coalescence. Meanwhile, local α-FeOOH enrichment developed in relatively oxygen-rich regions near the rust surface and inhibited lateral pit propagation. Thus, shifts in the wetting regime of the humid, salt-rich Pingtan atmosphere markedly regulate localized corrosion of Q355 steel by controlling rust-phase evolution and spatial distribution.