The soil pollution as a product of xenobiotics, industrial action, agricultural chemicals, or inappropriate disposal of waste can change the natural environment of soil indices and trigger life-threatening situations. Soil enzyme activity is the suitable bio-indicator or parameter for monitoring soil pollution due to their sensitivity that quickly responds to any soil disturbances. Also, they are known to play an essential role in maintaining soil health and a quality environment. This study aimed to determine the levels of enzyme activity in soil from polluted and unpolluted sites and study the relationship between the physicochemical properties and soil enzyme activity to manage soil pollution. Four selected enzymes (Urease, Invertase, Catalase, and Phosphatase) were examined for their activity from forty samples using the assay method for 24 h; the colorimetry spectrophotometer measured their activity. The obtained data revealed that Invertase activity was a predominant enzyme in all soil samples. Whereas, the urease activity had obtained in low amounts for all collection sites, especially on Site A1. Soil pH had discovered to range between 5.8 and 8.51, moisture content values recorded to vary from 0.12% to 9.09%, and soil organic carbon recorded to fluctuate between 0.08% and 1.54%. Urease and phosphatase activity correlated positively with all soil physicochemical properties except for moisture content, which correlated negatively (r = −0.297; p ≥ 0.05). The invertase activity negatively associated all soil physicochemical properties, excluding the moisture content that correlated positively and significantly with invertase activity. We noted that the dumpsite soil contains low enzyme activity levels, which might attribute to the type of waste disposed off. Also, only the phosphatase activity reported correlating positively with all examined physicochemical parameters entirely.

Heavy metals are unbreakable, and most of them are poisonous to animals and people. Metals are particularly concerning among environmental contaminants since they are less apparent, have extensive effects on ecosystems, are poisonous, and bioaccumulate in ecosystems, biological tissues, and organs. Therefore, there is a need to use biological agents and phytoremediation processes such as enzymes because they have a high potential for effectively transforming and detoxifying polluting substances. They can convert pollutants at a detectable rate and are potentially suitable for restoring polluted environments. We investigated heavy metal concentrations in different soil samples collected in four sections in Alice and determined the enzyme activity levels present in the soil. The Pearson correlation analysis was conducted to check whether there was any relationship between heavy metal concentrations and enzyme activities in the soil. Samples were randomly collected in three weeks, and the microwave digestion method was used for sample treatment and preparation. Quantitation was achieved by inductively coupled plasma mass spectrometry (ICP-MS). The enzyme assay through incubation method was implemented for discovering the four selected enzymes (urease, invertase, catalase, and phosphatase), and their activity levels were examined colorimetrically by colorimetry spectrophotometer. The ICP-MS results revealed 16 predominating elements, namely: Al, Ba, Ca, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Sr, and Zn, and the presence of a non-mental, which is phosphorus (P), and a metalloid in the form of silicon (Si) in all soil samples. Significant differences in metal concentrations were observed among the collection sites. The Al, Fe, K, Mg, and Ca concentrations were above WHO’s permissible limits. While Ba, Mn, Na, and P were in moderate concentration, Cu, Cr, Co, Zn, Sr, and Ni were in small amounts recorded mostly below the permissible values from WHO. Four soil enzyme activities were determined successfully (urease, invertase, phosphatase, and catalase). A negative non-significant correlation existed between urease, invertase, phosphatase enzyme activity, and the concentration levels of all selected metals (Al, Ba, Ca, Co, Cu, Fe, K, Mg, Mn, Na, Ni, Cr, Sr, and Zn. In contrast, the content of catalase activity was associated non-significantly but positively with the range of selected heavy metals. This study suggests proper monitoring of residences’ areas, which can provide detailed information on the impact of high heavy metal content on people’s health. They are easily dispersed and can accumulate in large quantities in the soil. The necessary implementation of waste management programs will help the municipality adopt a strategy that will promote recycling programs and protect the residence health from this threat.

The massive production of municipal solid waste presents a significant global challenge for sustainable urban development and maintaining citizens’ quality of life, requiring effective management and disposal strategies. Waste-to-energy incineration technology has become increasingly important as a solution that simultaneously addresses the growing volumes of municipal solid waste and rising energy needs worldwide. This comprehensive review examines the research findings on the effectiveness of incineration as a waste-to-energy conversion method. The primary goal was to conduct a thorough systematic review assessing WtE incineration effectiveness across several key areas: energy recovery efficiency, waste volume reduction capabilities, environmental impact, and economic feasibility. A comprehensive literature search was conducted across ScienceDirect and additional pertinent databases, utilizing appropriate search terms in accordance with the PRISMA framework. A total of 431 studies were systematically identified, published between 2015 and 2025, and only 25 relevant studies were included in this review. Researchers collected data focusing on energy recovery percentages, volume reduction rates, emission reductions, and economic performance metrics. The findings revealed that every study included in the analysis showed positive results for WtE incineration across various performance measures. This research discovered the feasibility of generating electrical power from garbage through WtE incineration processes. The projected energy yields, ranging from gigawatt-hours to kilowatt-hours, were quantified for several nations, including Mexico (11,681.64 GWh), Cambodia (1625.81 GWh), Bangladesh (187.04 GWh), South Africa (6944 GWh), Iran (17,678 GWh), Nigeria (10,000 GWh), Indonesia (2487 MWh), Algeria (11.6 MWh), China (2316.52 MWh), Iraq (203.917 MWh), Uganda (774 kWh), and Pakistan (675 kWh). Energy recovery efficiency demonstrated a wide range from 30% to 92.75%, with waste volume reduction consistently reaching 90–95% levels, significantly prolonging landfill operational lifespans. From an environmental perspective, technology achieved greenhouse gas emission reductions ranging from 30% to 87%. This dual-purpose approach makes it an attractive, sustainable solution for both waste management and renewable energy production. By adopting this approach, cities can address waste and energy issues while boosting economic growth and job creation. However, it also involves substantial costs, technical difficulties, and environmental hazards that necessitate meticulous oversight.

Heavy-metal contamination of the environment is a serious worldwide issue, as it presents dangerous threats to both human health and aquatic ecosystems. This has led to a paradigm shift toward the development of simple, user-friendly, and economically viable remediation technologies that are essential for addressing heavy-metal soil pollution and for the global preservation of the environment. This review provides a comprehensive overview of environmental remediation strategies using cyclodextrin (CD) and its derivatives. Additionally, this study examines the effectiveness of methylated gamma-cyclodextrin (M-γ-CD) as a modified oligosaccharide for the elimination of toxic elements from impure soil matrices. M-γ-CD has emerged as a potent agent for treating soil impurities with noxious metals. As a modified form of cyclodextrin, M-γ-CD features hydrophobic cavities that are particularly adept at forming inclusion complexes with heavy-metal ions, thereby cumulating the aqueous solubility and efficiency of pollutants in environmental applications and improving soil bioremediation. This paper also reviews the unique structural configuration of M-γ-CD, which significantly enhances the solubility and mobility of cyclodextrins and facilitates the extraction of noxious metal particles such as Ni, Cu, and Pb from soil matrices. Furthermore, M-γ-CD is a promising soil remediation agent due to its capacity to boost contaminant solubility, improve environmental safety, offer cost-effectiveness, ensure adaptability, and minimize impact on soil parameters. Therefore, M-γ-CD is a desirable agent for the elimination of toxic metal impurities from soil.

Heavy metals are unique environmental and industrial pollutants scattered naturally and found almost in all phases of the environment. In certain limited areas in several parts of the world, many people and animals have suffered from several severe diseases caused by trace elements or heavy metal deficiencies and their toxicities, unaware of their existence. The compounds of Pb and Cd are classified as human carcinogens by numerous regulatory agencies. The soil samples digested using the aqua regia method, and concentration quantified through the Inductively coupled plasma mass spectrometry (ICP-MS). In this study, Pb, Cd, and Hg concentrations were recorded high on the landfill site compared to the control site. Their concentration exceeded the permissible limits from WHO. Pb concentration ranges between 0.46ppm to 1.81ppm, Cd range from 0.98ppm and 0.56ppm, and Hg has a high concentration that varies between 6.28ppm and 1.69ppm. On the contrary, the Cu concentration reportable to be lesser than accepted WHO limits compared to the other two selected elements. The mean concentration of Cu ranges from 0.41 ppm to 0.72 ppm. Soil pH for both sites ranged from slightly acidic (6.67) to neutral (7.09), which falls within the normal range suggested by WHO. High Hg and Pb concentration in this study is a thing of concern. Undertaken this study to help address the soil pollution problem due to the illegal disposal of waste that results in metal accumulation.

Inadequate waste management and illegal trash dumping continue to be the leading causes of severe environmental pollution. Human exposure to harmful heavy metals has emerged as a serious health concern on the continent. Some people in Alice, a small town, grow their food in home gardens. They use animal manure and compost derived from soil obtained from landfills to enhance the fertility of the garden soil. Heavy metal heaps in garbage disposals are constantly present, releasing dangerous amounts of metal into the environment. The harmful effects of heavy metals on plants lead to unsanitary conditions and environmental problems. Animals and people who consume these vegetables may also be at risk for health problems. Assessing the soil’s enzyme activity can potentially lessen the negative effects of the accumulated pollutants and improve the soil’s overall health and quality. Soil enzymes are biologically active components that have a catalytic impact and are released from root exudates, crop residues, and animal remains. The activity of enzymes serves as an excellent bioindicator of soil cleanliness and quality because they are sensitive to heavy metals. X-ray diffraction (XRD) was used to quantify the mineral elements in soil using 40 kV parallel beam optics, 30 mA, and CuKα radiation. Meanwhile, the activity of the enzyme was essayed in different coupled substrates. Thirteen (13) clay minerals were found, including Talc 2M, Kaolinite 2M, and Chlorite Lawsonite Muscovite 2M1. The detected trace elements have high concentration levels that exceed the World Health Organization’s (WHO) allowed levels. The identified elements affected the enzyme activity at different levels. The Mn, Al, Si, V, Ti, and Ca negatively affect soil enzyme activity, specifically invertase (INV). However, the amount of Mg, K, Fe, and Zn showed a slightly positive effect on the same enzyme (INV). According to this view, these elements come from several sources, each with a particular impact on soil contamination and enzyme activity. High levels of heavy metals in this study may be due to improper waste disposal, limited recycling opportunities, lack of public awareness, and inadequate enforcement of waste management regulations. It is essential to employ Fourth Industrial Revolution (4IR) technologies, correct disposal techniques, suitable agricultural methods, preventive regulations, and efficient waste management to mitigate the negative effects of heavy metals on the environment.