The Chang’anpu Molybdenum deposit occurs in the monzogranite intrusions in the Lesser Khingan Mountains-Zhangguangcai Mountains metallogenic belt. Previous work focused on the study of deposits, including geological characteristics, mineralization time, S-Pb isotope, etc. However, systematic petrogeochemical study of monzogranite intrusion and comparative analysis with other porphyry deposits in the region are lacking. Three monzogranite dating samples yield LA-ICP-MS zircon weighted mean 206Pb/238U ages of 174.7 ± 1.3 Ma, 174.9 ± 1.4 Ma, and 174.3 ± 1.8 Ma, respectively, indicating that the magmatism occurred in the middle Jurassic of Mesozoic. The 14 monzogranite samples show alkali rich and relatively high silica content (up to 84.39%) with the differentiation index (DI) ranges from 86 to 96, showing that monzogranite have been subjected to fractional crystallization during its evolution; the depletion of Ba, Sr, P, Nb, Ti, and Eu also indicates that the rock has undergone crystallization fractionation, the monzogranite belong to the highly fractionated I-type. Positive εHf(t) values (6.72–8.85) and young TDM2 (551–673 Ma) of the monzogranite indicate that the formation of Chang’anpu monzogranite intrusion is related to the partial melting of juvenile lower crust, originated from the Mesoproterozoic depleted mantle. The magmatism and related Mo mineralization in the Chang’anpu deposit occurred in an active continental margin setting associated with westward subduction of the Paleo-Pacific plate beneath the Eurasian plate.
Liuhe gold orefield is being newly explored in the southeast part of the Jiapigou gold ore belt, and occurs in the Neoarchean basement composed of trondhjemite–tonalite–granodiorite (TTG). Zircon U–Pb data suggest that the ore-hosting magma emplacement in the Liuhe orefield mainly took place in two epochs: late Neoarchean to early Paleoproterozoic (ca. 2500 Ma) and early Jurassic of the Mesozoic era (ca. 170 Ma). The TTG rocks show higher A12O3 (12.58 to 15.71%) and Na2O/K2O ratios (1.16 to 2.9), and lower MgO (0.93 to 2.73%) and Mg# values, with positive Eu anomaly and low Y and Yb content, and high Sr/Y (22.3–79.6), and the plot in the adakite field in the Sr/Y-Y discriminant diagram belongs to the modern island-arc adakite rocks. Samples in this study are plotted in the pre-plate collision area in the R1-R2 discrimination diagram, and fall into the VAG and VAG + Syn-COLG field in the Rb-Y + Nb and Nb-Y diagram, respectively, indicating that the magmatism is related to plate subduction. The ore-bearing TTGs of the late Neoarchean to early Paleoproterozoic deposits were derived from the partial melting of mafic lower crustal caused by the underplating of basaltic magma on the island-arc or active continental margin before plate collision. The magmatism of the Dajiagou deposit occurred in active continental margin setting associated with the westward subduction of the paleo-Pacific plate beneath Eurasian Plate during the early Jurassic of Mesozoic period.
The West Kunlun represents one of the largest and most economically significant rare metal metallogenic belts in NW China. The newly discovered Dahongliutandong Li deposit is the first Li deposit identified within the Permian Huangyangling Group in this region, and its discovery has important implications for regional lithium exploration. In this study, whole-rock major and trace-element geochemistry and cassiterite U–Pb isotope data from both Li-poor and Li-rich pegmatites of the Dahongliutandong deposit were analyzed to constrain the mineralization age and tectonic setting. Geochemically, the pegmatites are characterized by high SiO2 (70.57–78.50 wt%), low TiO2, MnO, and MgO (<0.2 wt%), and strongly peraluminous signatures (A/CNK = 1.45–1.95). They exhibit coherent chondrite-normalized REE patterns with LREE enrichment and negative Eu anomalies (Eu/Eu* = 0.03–0.77), along with consistent enrichment in LILEs (e.g., Rb, U, K) and depletion in HFSEs (e.g., Nb, Ti) on primitive mantle-normalized spider diagrams, suggesting a common magmatic source or evolutionary path. Cassiterite U–Pb dating yielded consistent lower-intercept ages of 208 ± 11 Ma (MSWD = 0.86) for Li-poor pegmatites and 206 ± 5 Ma (MSWD = 1.7) for Li-rich pegmatites, both indicating Late Triassic mineralization. Combined with regional geology, these data suggest that Li mineralization was likely related to post-collisional extension following the closure of the Paleo-Tethys Ocean. This study provides new insights into regional rare metal mineralization in the West Kunlun orogenic belt.