Regenerative medicine is a field that aims to influence and improvise the processes of tissue repair and restoration and to assist the body to heal and recover. In the field of hard tissue regeneration, bio-inert materials are being predominantly used, and there is a necessity to use bioactive materials that can help in better tissue–implant interactions and facilitate the healing and regeneration process. One such bioactive material that is being focused upon and studied extensively in the past few decades is bioactive glass (BG). The original bioactive glass (45S5) is composed of silicon dioxide, sodium dioxide, calcium oxide, and phosphorus pentoxide and is mainly referred to by its commercial name Bioglass. BG is mainly used for bone tissue regeneration due to its osteoconductivity and osteostimulation properties. The bioactivity of BG, however, is highly dependent on the compositional ratio of certain glass-forming system content. The manipulation of content ratio and the element compositional flexibility of BG-forming network developed other types of bioactive glasses with controllable chemical durability and chemical affinity with bone and bioactivity. This review article mainly discusses the basic information about silica-based bioactive glasses, including their composition, processing, and properties, as well as their medical applications such as in bone regeneration, as bone grafts, and as dental implant coatings.

Supercapacitors are energy storage devices with high power density, rapid charge/discharge rate, and excellent cycle stability. Carbon-based supercapacitors are increasingly attracting attention because of their large surface area and high porosity. Carbon-based materials research has been recently centered on biomass-based materials due to the rising need to maintain a sustainable environment. Cellulose and lignin constitute the major components of lignocellulose biomass. Since they are renewable, sustainable, and readily accessible, lignin and cellulose-based supercapacitors are economically viable and environmentally friendly. This review aims to systematically analyze published research findings on electrospun lignin, cellulose, and lignin/cellulose nanofibers for use as supercapacitor electrode materials. A rigorous scientific approach was employed to screen the eligibility of relevant articles to be included in this study. The research questions and the inclusion criteria were clearly defined. The included articles were used to draw up the research framework and develop coherent taxonomy of literature. Taxonomy of research literature generated from the included articles was classified into review papers, electrospun lignin, cellulose, and lignin/cellulose nanofibers for use as supercapacitor electrode materials. Furthermore, challenges, recommendations, and research directions for future studies were equally discussed extensively. Before this study, no review on electrospun lignin/cellulose nanofiber-based supercapacitors has been reported. Thus, this systematic review will provide a reference for other researchers interested in developing biomass-based supercapacitors as an alternative to conventional supercapacitors based on petroleum products.

We report growth of quaternary Cu₂ ZnSnS₄ (CZTS) thin films prepared by the electrochemical deposition from salt precursors containing Cu (II), Zn (II) and Sn (IV) metals. The influence of different sulfurization times t (t = 75, 90, 105 and 120 min) on the structural, compositional, morphological and optical properties, as well as on the electrical properties is studied. The films sulfurized 2 hours showed a prominent kesterite phase with a nearly stoichiometric composition. Samples were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM) and Raman and UV-VIS-NIR spectrometer at different stages of work. X-ray diffraction and Raman spectroscopy analyses confirmed the formation of phase-pure CZTS films. (FESEM) shows that compact and dense morphology and enhanced photo-sensitivity. STEM - EDS elemental map of CZTS cross-section confirms homogeneous distribution. From optical study, energy gap was enlarged with a changed sulfurization times in the range of 1.37–1.47 eV.

Composite polymer electrolyte (CPE) based on polyvinyl alcohol (PVA) polymer, potassium carbonate (K₂CO₃) salt, and silica (SiO₂) filler was investigated and optimized in this study for improved ionic conductivity and potential window for use in electrochemical devices. Various quantities of SiO₂ in wt.% were incorporated into PVA-K₂CO₃ complex to prepare the CPEs. To study the effect of SiO₂ on PVA-K₂CO₃ composites, the developed electrolytes were characterized for their chemical structure (FTIR), morphology (FESEM), thermal stabilities (TGA), glass transition temperature (differential scanning calorimetry (DSC)), ionic conductivity using electrochemical impedance spectroscopy (EIS), and potential window using linear sweep voltammetry (LSV). Physicochemical characterization results based on thermal and structural analysis indicated that the addition of SiO₂ enhanced the amorphous region of the PVA-K₂CO₃ composites which enhanced the dissociation of the K₂CO₃ salt into K⁺ and CO₃²⁻ and thus resulting in an increase of the ionic conduction of the electrolyte. An optimum ionic conductivity of 3.25 × 10⁻⁴ and 7.86 × 10⁻³ mScm⁻¹ at ambient temperature and at 373.15 K, respectively, at a potential window of 3.35 V was observed at a composition of 15 wt.% SiO₂. From FESEM micrographs, the white granules and aggregate seen on the surface of the samples confirm that SiO₂ particles have been successfully dispersed into the PVA-K₂CO₃ matrix. The observed ionic conductivity increased linearly with increase in temperature confirming the electrolyte as temperature-dependent. Based on the observed performance, it can be concluded that the CPEs based on PVA-K₂CO₃-SiO₂ composites could serve as promising candidate for portable and flexible next generation energy storage devices.