In this work, resistive switching in pulsed laser deposited ferroelectric lead-free 0.5Ba(Zr _0.2 Ti _0.8 )O ₃ –0.5(Ba _0.7 Ca _0.3 )TiO ₃ (0.5BZT–0.5BCT) thin films was investigated. This study reveals that films grown at 5.5 J cm ⁻² have shown optimal ferroelectric and resistive switching response, which are attributed to high tetragonality, large grain size and less defect concentration. Au/0.5BZT–0.5BCT/Pt capacitors show the electroforming free resistive switching that is explained based on the polarization modulation of the Schottky-like barrier at the 0.5BZT–0.5BCT/Au interface. The polarization induced resistive switching is evidenced by its disappearance as the temperature increases to the Curie temperature. The capacitor based on film grown at 5.5 J cm ⁻² shows resistive switching characterized by high switching ratio of 10 ⁶ at a low set/reset voltage ≈1 V, and by a stable memory window, which are highly required for memory applications.

Surgicel^® (regenerated oxidized cellulose) is a bio-absorbable hemostatic material widely applied to prevent surgery-derived adhesions. Some critical issues have been reported associated with this biomaterial, which we aimed to overcome by producing bacterial nanocellulose (BNC) membranes with hemostatic activity, through electrochemical oxidation using the tetramethylpiperidine-1-oxyl (TEMPO) radical. Samples were characterized by FTIR, NMR, SEM, XRD and their degree of polymerization. The oxidation degree was evaluated by titration of the carboxyl groups and the hemostatic behavior by whole-blood-clotting assays. In vitro and in vivo biodegradability of oxidized BNC membranes were evaluated and compared with that of Surgicel^®. The oxidation degree increased from 4% to 7% and up to 15%, corresponding to an applied charge of 400, 700 and 1200 Coulombs, respectively. The oxidized BNC preserved the crystallinity and the 3D nano-fibrillar network, and demonstrated hemostatic activity, although not as effective as that of Surgicel^®. In vivo assays demonstrated that the oxidized membranes did not induce an inflammatory response, revealing a good biocompatibility. However, non-degraded oxidized BNC was still detected at the implantation site after 56 days.

This work reports the changes in structure and lattice dynamics induced by substituting the Jahn-Teller-active $\mathrm{M}{\mathrm{n}}^{3+}$ ion by the Jahn-Teller-inactive $\mathrm{F}{\mathrm{e}}^{3+}$ in $\mathrm{TbM}{\mathrm{n}}_{1\text{−}x}\mathrm{F}{\mathrm{e}}_x{\mathrm{O}}_3$ over the full composition range. The structural analysis reveals that the amplitude of the cooperative Jahn-Teller distortion decreases linearly from $x=0$ (pure $\mathrm{TbMn}{\mathrm{O}}_3)$ to $x=0.5$, where it is completely suppressed. We then correlate this evolution with the behavior of the Raman modes across the solid solution. In particular, we show that the Raman modes associated with the rotation of octahedra, whose wave number is commonly considered to scale linearly with the tilt angles in orthorhombic Pnma perovskites, are also sensitive to the amplitude of the Jahn-Teller distortion.