We present a study of pressure and temperature evolution in the passive continental margin under the Oman Ophiolite using numerical basin models calibrated with thermal maturity data, fluid-inclusion thermometry, and low-temperature thermochronometry and building on the results of recent work on the tectonic evolution. Because the Oman mountains experienced only weak post-obduction overprint, they offer a unique natural laboratory for this study. Thermal maturity data from the Adam Foothills constrain burial in the basin in front of the advancing nappes to at least 4 km. Peak temperature evolution in the carbonate platform under the ophiolite depends on the burial depth and only weakly on the temperature of the overriding nappes, which have cooled during transport from the oceanic subduction zone to emplacement. Fluid-inclusion thermometry yields pressure-corrected homogenization temperatures of 225 to 266 ^∘C for veins formed during progressive burial, 296–364 ^∘C for veins related to peak burial, and 184 to 213 ^∘C for veins associated with late-stage strike-slip faulting. In contrast, the overlying Hawasina nappes have not been heated above 130–170 ^∘C, as witnessed by only partial resetting of the zircon $\left(\mathrm{U}-\mathrm{Th}\right)/\mathrm{He}$ thermochronometer. In combination with independently determined temperatures from solid bitumen reflectance, we infer that the fluid inclusions of peak-burial-related veins formed at minimum pressures of 225–285 MPa. This implies that the rocks of the future Jebel Akhdar Dome were buried under 8–10 km of ophiolite on top of 2 km of sedimentary nappes, in agreement with thermal maturity data from solid bitumen reflectance and Raman spectroscopy. Rapid burial of the passive margin under the ophiolite results in sub-lithostatic pore pressures, as indicated by veins formed in dilatant fractures in the carbonates. We infer that overpressure is induced by rapid burial under the ophiolite. Tilting of the carbonate platform in combination with overpressure in the passive margin caused fluid migration towards the south in front of the advancing nappes. Exhumation of the Jebel Akhdar, as indicated by our zircon $\left(\mathrm{U}-\mathrm{Th}\right)/\mathrm{He}$ data and in agreement with existing work on the tectonic evolution, started as early as the Late Cretaceous to early Cenozoic, linked with extension above a major listric shear zone with top-to-NNE shear sense. In a second exhumation phase the carbonate platform and obducted nappes of the Jebel Akhdar Dome cooled together below ca. 170 ^∘C between 50 and 40 Ma before the final stage of anticline formation.

Tungsten mineralization in hydrothermal quartz veins from the Nyakabingo,Gifurwe and Bugarama deposits in central Rwanda occurs as the iron-rich endmember ofthe wolframite solid solution series (ferberite) and in the particular form of reinite, whichrepresents a pseudomorph of ferberite after scheelite. Primary ferberite, reinite and latesecondary ferberite are characterized by their trace element chemistry and rare earthelement patterns. The replacement of scheelite by ferberite is also documented in the traceelement composition. Primary ferberite shows high Mg, Zn, Sc, V, Nb, In and Snconcentrations, but very low Ca, Pb, Sr and Ba contents. Reinite and late secondaryferberite display an uncommon trace element composition containing high concentrationsof Ca, Pb, Sr, Ba, As and Ga, but very low levels in Sn, Zr, Hf, In, Ti, Sc, Nb, Ta, Mg andZn. Late secondary ferberite replacing primary ferberite is characterized by additionalenrichments in Bi, Pb, As and Sb. The rare earth element patterns of reinite and secondaryferberite are also similar to hydrothermal scheelite. The formation of the tungsten depositsin central Rwanda is interpreted to be epigenetic in origin, and the hydrothermalmineralizing fluids are related to the intrusion of the G4-granites.

We studied an exhumed high-pressure cell in outcrops of Cretaceous carbonates on the southern flank of Jabal Shams in the Oman Mountains. This more than 2 km thick sedimentary pile contains reservoir and source rocks in northern Oman and the United Arab Emirates. It develops a complex and rapidly changing anisotropy, due to mechanical stratigraphy and several generations of pervasive regional fault and fracture sets. Calcite cement healed faults and fractures before the next sets were formed. Burial extension within a high fluid-pressure environment led to the formation of four fracture generations by an anticlockwise rotating stress field. This was followed by bedding-parallel shear under lithostatic fluid-pressure conditions at a minimum temperature of 134–221°C deduced from primary and pseudosecondary fluid inclusions in quartz. The high pressure cell was drained along dilatant normal faults that were also repeatedly cemented and reactivated. The rapidly changing mechanical anisotropy, in combination with a chemically reactive system formed a complex feedback system in which the mechanical strength, strain and the permeability underwent major changes in this coupled thermal, hydraulic, and mechanical (THM) system.