Novel mycelium-based biocomposites (MBB) were obtained from local agricultural (hemp shives) and forestry (wood chips) by-products which were bounded together with natural growth of fungal mycelium. As a result, hemp mycocomposites (HMC) and wood mycocomposites (WMC) were manufactured. Mechanical, water absorption and biodegradation properties of MBB were investigated. MBB were characterized also by ash content and elemental composition. The results of MBB were compared with the reference materials such as the commercial MBB material manufactured by Ecovative® Design (EV), hemp magnesium oxychloride concrete (HC) and cemented wood wool panel (CW), manufactured by CEWOOD®. The mechanical properties of HMC and WMC showed that the bending strength difference was about 30%, with a better result for HMC. Compression strength was better for WMC by about 60% compared to that of HMC. The mechanical strength of HMC and HC materials was equal; both materials contained hemp shives but differed by the binding material. Water absorption and volumetric swelling tests showed that HMC and WMC could be considered as potential biosorbents. Ash content and elemental analysis showed that reference materials (CW, HC) contained significant amounts of inorganic compounds that decreased the biodegradation rate, compared to the case of HMC and WMC materials. The biodegradation results of HMC and WMC, after 12 weeks, revealed a mass loss (ML) above 70%, while in the case of EV, HC and CW, it was about 60%, 17% and only 6%, respectively. MBB were completely biodegradable.
A newly developed thermo-hydro treatment (THT) for use in a one-stage heat treatment process was examined by focusing on the form stability-related properties of European aspen (Populus tremula), birch silver (Betula pendula), and gray alder (Alnus incana). In particular, wood specimens were subjected to THT in a saturated steam atmosphere in a pilot-scale autoclave heated between 140 and 180°C for 1–3 h. Several parameters of untreated and treated samples after several soaking and drying cycles were compared, namely, the changes in the volumetric swelling, swelling in the radial and tangential directions, cell wall total water capacity, and anti-swelling efficiency (ASE). Due to repeated wetting in the cyclic water submersion-drying test, the original ASE of 73% decreased to 65% (180°C for 1 h), and the original ASE of 33% decreased to 5% (140°C for 1 h). Wood modified at 170°C presented good results that were not significantly lower than wood treated at higher temperatures while consuming less energy to deliver ASE improvement and was selected as optimum. To increase the ASE by 1%, the amount of energy consumed was decreased by 41%, 39%, and 17% compared with the treatment regimes of 160°C for 1 h, 160°C for 3 h, and 180°C for 1 h, respectively. The new THT regime led to improved long-term dimensional stability due to the cross-linking of cell wall polymers, which resulted in increased cell wall rigidity.
This study investigated the effect of phenol-formaldehyde (PF) resin treatment on the weathering stability and biological durability of birch plywood. Silver birch (Betula pendula) veneers were vacuum-pressure impregnated with four different PF resins with average molecular weights (Mw) of 292 (resin A), 528 (resin B), 703 (resin C), and 884 g/mol (resin D). The aging properties of PF resin modified birch plywood were analyzed using artificial weathering with ultraviolet (UV) light, UV and water spray, and weathering under outdoor conditions. The same combinations of PF-treated plywood specimens were then tested in soil-bed tests to determine their resistance against soft-rot wood decay. It was not possible to compare weathering processes under artificial conditions to processes under outdoor conditions. However, the weathering stability of birch plywood treated with PF resins A, B, and C, scored better than plywood treated with commercial resin D (regardless of solid content concentration [%]). Results from unsterile soil bed tests showed improvements in resistance to soft-rot wood decay compared to untreated plywood and solid wood. Mass loss [%] was lowest for birch plywood specimens treated with resin of highest solid content concentration (resin D, 20%). Provisional durability ratings delivered durability class (DC) ratings of 2–3, considerably improved over untreated solid wood and untreated birch plywood (DC 5).