Background: This study explores how different post-processing methods affect the mechanical properties and degree of conversion of 3d-printed polyurethane aligners made from Tera Harz TC-85 resin. Methods: Using Fourier-transform infrared (FTIR) spectroscopy, the degree of conversion of liquid resin and post-processed materials was analyzed. This investigation focused on the effects of various post-curing environments (nitrogen vs. air) and rinsing protocols (centrifuge, ethanol, isopropanol, and isopropanol + water). The assessed mechanical properties were flexural modulus and hardness. Results: The degree of conversion showed no significant variance across different groups, though the polymerization environment influenced the results, accounting for 24.0% of the variance. The flexural modulus varied considerably, depending on both the rinsing protocol and the polymerization environment. The standard protocol (centrifugation followed by nitrogen polymerization) exhibited the highest flexural modulus of 1881.22 MPa. Hardness testing revealed significant differences, with isopropanol treatments showing increased resistance to wear in comparison to the centrifuge and ethanol rinse treatments. Conclusions: This study conclusively demonstrates the adverse effects of oxygen on the polymerization process, underscoring the critical need for an oxygen-free environment to optimize material properties. Notably, the ethanol rinse followed by nitrogen polymerization protocol emerged as a viable alternative to the conventional centrifuge plus nitrogen method.

Vat photopolymerization 3D printing, including stereolithography (SLA), digital light processing (DLP), and masked SLA (mSLA), has transformed dental device fabrication by enabling precise and customizable components. However, the rheological behavior of photopolymer resins is a critical factor that governs the printability, accuracy, and performance of printed parts. This review surveys the role of viscosity, shear-thinning, and thixotropy in defining the “printability window” of dental resins and explores the relationship between these properties and the formulation and final material performance. Rheological characterization using rotational rheometry provides key insights, with shear rate sweeps and thixotropy tests quantifying whether a resin behaves as Newtonian or pseudoplastic. The literature shows that optimal printability typically requires resins with low to moderate viscosity at shear, moderate thixotropy for stability, and formulations balanced between high-strength oligomers and low-viscosity diluents. The addition of fillers modifies the viscosity and dispersion, which can improve reinforcement but may reduce print resolution if not optimized. Thermal and optical considerations are also coupled with rheology, affecting the curing depth and accuracy. In conclusion, controlling resin rheology is essential for bridging material formulation with reliable clinical outcomes, guiding both resin design and printer process optimization in modern dental applications.

A broader application of biocomposites still faces many challenges regarding structural integrity, environmental resistance, and biodegradability. These issues are particularly important when their marine applications are considered. Therefore, this paper seeks to address the hygroscopicity, mechanical properties, and biofouling resistance of biocomposites made of epoxy resin with 28 m% bio-based carbon content reinforced with flax and hemp fibers. A series of experiments are performed to acquire water absorption rates, saturation limits, mass increase, tensile and flexural properties, interlaminar shear strength, impact resistance, and mass gain due to biofouling. All tests of mechanical properties are conducted before and after immersion in seawater. The acquired saturation limits of flax/epoxy and hemp/epoxy biocomposites amount to 7.5% and 9.8%, respectively. The water uptake causes the tensile and flexural properties to decrease by 26–74%, while interlaminar and impact strength increase for flax/epoxy and decrease for hemp/epoxy biocomposites. In addition, it is observed that in almost all cases, flax/epoxy has superior properties compared with hemp/epoxy biocomposites. It is expected that this research will motivate naval architects and classification societies to consider biocomposites as prospective hull materials that provide both structural integrity and environmental sustainability.

Fossil fuel combustion is a major source of Greenhouse Gases (GHGs), which cause global warming. To prevent further increases in anthropogenic GHGs, the global community needs to take action in each segment of the economy, including the shipping sector. Among different measures for reducing shipping emissions, the most promising one is the replacement of conventional marine fuels with alternatives. According to the International Maritime Organisation’s regulations, ships engaged in international shipping need to reduce their annual emissions by at least 50% by 2050. However, this does not apply to fishing vessels, which are highly dependent on fossil fuels and greatly contribute to air pollution. This paper investigates the environmental footprint of a fishing vessel (purse seiner) through the implementation of various alternative fuels. Within the research, Life-Cycle Assessments (LCAs) and Life-Cycle Cost Assessments (LCCAs) are performed, resulting in life-cycle emissions and lifetime costs for each alternative, which are then compared to a diesel-powered ship (baseline scenario). The comparison, based on environmental and economic criteria, highlighted methanol as the most suitable alternative for the purse seiner, as its use onboard resulted in 22.4% lower GHGs and 23.3% lower costs in comparison to a diesel-powered ship.

In this study, poly(vinyl-alcohol) (PVA)/chitosan (CS) polymer blend films with different amounts of CS (0, 5, 20 and 35 wt. %) crosslinked by glutaraldehyde (GA) were prepared. The structure and properties of the prepared polymer films were studied by means of dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), and the time-lag permeation technique. The DMA analysis showed that CS reduces the crystallinity degree of PVA, leading to a higher amount of the amorphous phase contributing to the α relaxation that corresponds to the glass-to-rubber transition. However, the mobility of the amorphous phase can be restricted with crosslinking with 1 wt. % GA. Interaction between the PVA and the CS was confirmed by DCS analysis. Additionally, the influence of the CS and crosslinking on the permeation of nitrogen molecules was investigated. The permeation was examined by the time-lag method. It was found that the addition of CS and GA to PVA improves barrier properties.

The surface similarity phenomenon describes how users apply maintenance habits from one material to another based on perceived similarities. Cleaning protocols for thermoformed aligners are often used for three-dimensional (3D) printed aligners, despite their different material properties. This study aimed to evaluate how such practices impact the physical and aesthetic properties of 3D-printed aligners. A total of 84 polyurethane-based specimens were fabricated using direct light processing. They were divided into three groups: brushing only, brushing with toothpaste, and immersion in an alkaline solution (Corega). Each protocol simulated two weeks of daily cleaning. Surface roughness was assessed via profilometry and AFM, hardness via the Ball Indentation Method, and color change via VITA Easyshade before and after cleaning. Water absorption was measured daily over 14 days during immersion in either Corega or saline. Statistical analyses included Wilcoxon signed-rank tests, paired t-tests, one-way ANOVA with LSD post-hoc tests, and Kruskal-Wallis tests with post-hoc Dunn test. Brushing with toothpaste caused the greatest increase in surface roughness (ΔSa = 37.45 nm), followed by brushing alone (ΔSa = 10.55 nm); Corega slightly reduced roughness (ΔSa = -4.86 nm). Surface hardness increased after brushing but decreased with Corega (p < 0.05). No significant ΔE color differences were found, though “b” values decreased with brushing (p = 0.012). Water absorption stabilized at 8.47% in saline, while Corega immersion led to peak absorption on day 8 before degradation (p < 0.001). Cleaning methods designed for thermoformed aligners can alter surface properties and degrade 3D-printed aligners. Tailored cleaning protocols are essential to preserve their integrity and functionality.