In this work, the authors present the possibility of modification of polymer membranes by TiO₂ + AgO coating created by the magnetron sputtering method. The two-component TiO₂ + AgO coating can improve and shape new functional properties such as bactericidal and photocatalytic properties. The influence of magnetron power changes on the structure of the membrane was investigated as well. The structure and elemental composition of TiO₂ + AgO coatings were analyzed using SEM and EDS technique. All deposited coatings caused a total inhibition of the growth of two investigated colonies of Escherichia coli and Bacillus subtilis on the surface. The photocatalytic properties for membranes covered with oxide coatings were tested under UV irradiation and visible light. The filtration result show that polymer membranes covered with two-component TiO₂ + AgO coatings have a permeate flux similar to the non-coated membranes.

Microfiltration (MF) membranes have been widely used for the separation and concentration of various components in food processing, biotechnology and wastewater treatment. The deposition of components from the feed solution and accumulation of bacteria on the surface and in the membrane matrix greatly reduce the effectiveness of MF. This is due to a decrease in the separation efficiency of the membrane, which contributes to a significant increase in operating costs and the cost of exploitative parts. In recent years, significant interest has arisen in the field of membrane modifications to make their surfaces resistant to the deposition of components from the feed solution and the accumulation of bacteria. The aim of this work was to develop appropriate process parameters for the plasma surface deposition of silver oxide (AgO) on MF polyamide membranes, which enables the fabrication of filtration materials with high permeability and antibacterial properties.

A novel approach of the deposition of two-component coating consisting of TiO₂ and CuO on polymer membranes by MS-PVD method was presented in this work. This confirmed the possibility of using thin functional coatings for the modification of polymer membranes. The influence of technological parameters of the coating deposition on the membrane’s structure, chemical composition and functional properties (hydrophilic, photocatalytic and bactericidal properties) were analyzed using SEM. Model microorganism such as Escherichia coli and Bacillus subtilis have been used to check the antibacterial properties. The results indicated that doping with CuO highlights the potential of bactericidal efficiency. The surface properties of the membranes were evaluated with the surface free energy. For evaluating photocatalytic properties, the UV and visible light were used. The filtration tests showed that polymer membranes treated with two-component TiO₂ + CuO coatings have a permeate flux similar to the reference material (non-coated membrane). The obtained results constitute a very promising perspective of the potential application of magnetron sputtering for deposition of TiO₂ + CuO coatings in the prevention of biofouling resulted from the membrane filtration of dairy wastewater.

Polymer membranes play an important role in various filtration processes. The modification of a polyamide membrane surface by one-component Zn and ZnO coatings and two-component Zn/ZnO coatings is presented in this work. The technological parameters of the Magnetron Sputtering-Physical Vapor Deposition method (MS-PVD) for the coatings deposition process show an impact on the influence on the membrane’s surface structure, chemical composition, and functional properties. The characterization of surface structure and morphology were analyzed by scanning electron microscopy. In addition, surface roughness and wettability measurements were also made. For checking the antibacterial activity, the two representative strains of bacteria Escherichia coli (Gram-negative) and Staphylococcus aureus (Gram-positive) were used. The filtration tests showed that polyamide membranes covered with three types of coatings, one-component Zn coatings, ZnO coatings, and two-component Zn/ZnO coatings, presented similar properties. The obtained results show that using the MS-PVD method for modification of the membrane’s surface is a very promising perspective in the prevention of biofouling.

Anti-wear coatings obtained through PVD methods may significantly increase the durability of cutting tools by impacting their wear mechanisms. This study presents and discusses the results of studies on the impact of the thermal conductivity of PVD coatings on the intensity of the built-up edge (BUE) and built-up layer (BUL) formation in Inconel 600 alloy machining processes. The authors determine the microstructure, phase structure, mechanical properties (hardness, Young’s modulus, and adhesion), and thermal conductivity of different PVD coatings selected for the purpose of the study and varying in terms of conductivity—i.e., AlCrTiN and AlCrTiN/BN. Machining processes were carried out under controlled conditions using VBGT160404-M3 cutting inserts with AlCrTiN and AlCrTiN/BN coatings deposited on their surface. The authors prove that the adjustment of the thermal conductivity of PVD coatings to the thermal conductivity of the tool and machined materials can help change the direction of heat flow to cool the cutting zone more effectively. The study results presented in this article show that the deposition of the AlCrTiN/BN coating reduces the friction wear on the tool flank by over 70% and lowers the intensity of BUE and BUL formation processes on the face by 10%, compared to the AlCrTiN coating.

In this paper, silver oxide (AgO) and copper oxide (CuO) coatings are placed on a single sputtering target with the direct-current magnetron sputtering (DCMS) and high-power impulse magnetron sputtering (HIPIMS) methods. All the tested coatings are obtained in a reactive process using a metallic target made by the Kurt Lesker company. The investigated coatings are deposited at room temperature on substrates made of pure iron (ARMCO) and polypropylene (PP) without substrate polarization. The deposition time for all the coatings is the same. The results of SEM and TEM investigations clearly show that using the HIPIMS method for the deposition of AgO and CuO coatings reduces their thickness and increases their structure density. Coatings produced with the HIPIMS method are characterized by a higher hardness and Young’s modulus. The value of hardness for AgO and CuO coatings deposited by the HIPIMS method is around 50% higher for AgO coatings and around 24% higher for CuO coatings compared to the coatings obtained by the DC method. This is also true of Young’s modulus values, which are around 30% higher for AgO coatings and 15% higher for CuO coatings produced by the HIPIMS method compared to those of coatings obtained with the DC method. AgO and CuO coatings deposited with both the methods (HIPIMS and DCMS) showed 100% reduction in the viability of two reference laboratory bacteria strains—Escherichia coli (Gram−) and Staphylococcus aureus (Gram+)—on both types of substrates. Additionally, these coatings are characterized by their hydrophobic properties, which means that they can create a protective barrier, making it difficult for bacteria to stick to the surface, limiting their development and preventing the phenomenon of biofouling. The HIPIMS technology allows for the deposition of coatings with better mechanical properties than those produced with the DCMS method, which means that they are more resistant to brittle fractures and wear and have very good antimicrobial properties.