Background: Anthropogenic activities have clearly affected the environment, with irreversible and destructive consequences. Mining activities have a significant negative impact, primarily on soil, and then on human health. The negative impact of the first mining activities is represented even today in the soils of those localities. Research shows that, for different types of mines, the concentrations of potentially toxic elements (PTEs) are high, especially in antimony, multi-metal and lead–zinc mines, which have adverse effects on the environment and then on human health and the economy. A large flood in 2014 in Western Serbia resulted in the breaking of the dam of the processed antimony ore dump of the former antimony mine, causing toxic tailings to spill and pollute the downstream area. Due to this accident, tailings material flooded the area downstream of the dump, and severely affected the local agriculture and population. Methods: Potentially toxic elements content, pollution indices and health indices were determined in soil samples from the flooded area, using referenced methodologies. The sources and routes of pollutants and risks were determined and quantified using statistical principal component analysis, positive matrix factorisation, and a Monte Carlo simulation. Results: The main source of As, Cd, Hg, Pb, Sb and Zn in the upper part of the study area was the tailing material. Based on the pollution indices, about 72% of the studied samples show a high risk of contamination and are mainly distributed immediately downstream of the tailings dump that was spilled due to heavy rainfall. Conclusions: Although the content of the PTEs is high, there is no non-carcinogenic risk for any PTEs except As, for which a threshold risk was determined. There is no carcinogenic risk in the study area.

Diffuse water pollution from agriculture (DWPA) is one of the major factors causing water pollution in Lakes Palić and Ludaš, the two largest shallow lakes of the Pannonian Basin in Serbia. These two lakes are protected under national and international law. On the basis of the number of strictly protected bird species, Ludaš Lake has been classified as a wetland of international importance since 1977 (Ramsar site 3YU002); in 2021, both lakes were nominated as potential Natura 2000 areas. Despite the degree of protection and ecological significance of the area, agricultural land prevails. By a process of land expropriation during 2019, the buffer zone began to expand around the lakes, which should lead to a reduction in pollution. One of the goals of buffer-zone development is to enhance and restore the ecological connectivity of the remaining forest-steppe habitats. During the expropriation process, soil was sampled to record areas with the highest pollution. This paper assesses the environmental risk caused by phosphorus, nitrogen, and the accumulation of heavy metals (Zn, Cu, Pb, Cr, Ni, Mn, Cd, and Hg). For each heavy metal, the corresponding pollution indices (Igeo, PI, EF, Eri, RI, Nemerow) and soil contamination level were calculated. Pollution indices indicate the ecological risk under the influence of heavy metals in the following order: Cd > Cu > Ni > Zn > Pb > Cr > Hg. Results showed that concentrations of Cd exceeded the maximal permissible concentration in all examined soil samples, and high ecological risk areas were determined. High concentrations of nitrogen, phosphorus, and potassium were detected, which could be as a result of intensive agricultural activity. Current conservation measures in this area have not provided adequate protection of the natural environment. Accordingly, existing measures must be controlled or new, more restrictive measures must be prescribed.

Geostatistical methods are important in analyzing natural resources providing input data for complex mathematical models that address environmental processes and their spatial distribution. Ten interpolation methods and one empirical-based classification grounded in empirical knowledge, with a total of 929 soil samples, were used to create the most accurate spatial prediction maps for clay, sand, humus, and soil depth in Montenegro. These analyses serve as a preparatory phase and prioritize the practical application of the obtained results for the implementation and improvement of the MEDALUS model. This model, used to assess sensitivity to land degradation, effectively integrates into broader current and future research. The study emphasizes the importance of incorporating auxiliary variables, such as topography, climate, and vegetation data, enhancing explanatory power and accuracy in delineating the environmental characteristics, ensuring better adaptability to the studied area. The results were validated by the coefficient of determination (R²) and root mean square error (RMSE). For the clay, EBKRP (empirical Bayesian kriging regression prediction) achieved R² = 0.35 and RMSE = 6.95%, for the sand, it achieved R² = 0.34 and RMSE = 17.38%, for the humus, it achieved R² = 0.50 and RMSE = 3.80%, and for the soil depth, it achieved R² = 0.76 and RMSE = 5.36 cm. These results indicate that EBKRP is the optimal method for accurately mapping soil characteristics in future research in Montenegro.

Wetlands store large amounts of soil organic carbon stock (SOCS), making them crucial for global climate regulation. However, climate change, poor management, and weak protection policies threaten these stocks. To assess the contribution of different wetland types for national and international climate targets and to monitor the effectiveness of protection measures, additional research is required. Therefore, we assessed SOCS and disturbances from climate change, land use/land cover (LULC), and soil chemical composition in saline and eutrophic Ramsar sites in Serbia. Analyzing a total of 96 samples, we accounted for soil depth, reference soil group (RSG), and habitat/vegetation type. Mean SOCS in the saline site ranged from approximately 36 t·ha⁻¹ at 0–30 cm to 26 t·ha⁻¹ at 30–60 cm, whereas values were much higher for the eutrophic sites, ranging from 81 to 82 t·ha⁻¹ at 0–30 cm and 47–63 t·ha⁻¹ at 30–60 cm. Differences between groups for the whole soil columns (0–60 cm) were significant at the 0.1% level. While SOCS generally decreases with depth, it showed notable local variability, including occasional instances at deeper layers, indicating complex environmental and anthropogenic influences. Spatial mapping of soil chemistry parameters (pH, humus, P₂O₅, and K₂O) along with land use/land cover (LULC) data revealed nutrient dynamics influenced by agricultural activities. An analysis of regional climate data revealed temperature increases relative to the reference period of 1971–2000 by 0.5 °C for the decade 2001–2010 and of 1.5 °C for 2011–2020. Climate projections under the RCP4.5 and 8.5 scenarios predict further warming trends, as well as increased rainfall variability and drought risks. The results of our study contribute to quantifying the important, though variable, contribution of wetland sites to global climate regulation and show the influence of geogenic, pedogenic, and anthropogenic factors on SOCS. National policies should be adapted to safeguard these stocks and to limit negative effects from surrounding agricultural areas, as well as to develop strategies to cope with expected regional climate change effects.

The glass industry contributes to long-term soil contamination. This study assesses the impact of over 150 years of industrial activity and over a century of glassmaking processes in the Serbian Glass Factory in Paraćin. Focusing on potentially toxic elements (PTEs) and polycyclic aromatic hydrocarbons (PAHs), ecological and human health risks were evaluated. Sampling was conducted at 34 locations within the factory area, including 33 soil samples (0–30 cm) and one industrial waste (IW) sample. Soil analyses indicate that Zn, Ni, Cu, and Cd exceeded both the maximum permissible concentrations (MPCs) and remediation values (RVs) in many samples, while As and Hg showed fewer exceedances. Based on the Potential Ecological Risk Index (RI), about 33% of soil samples were moderately to highly polluted, and Cd, Pb, As, and Hg were identified as the main contributors. High levels of PAHs and PTEs reflect the cumulative impact of long-term industrial operations, a historical fire, and secondary sources, including traffic-related emissions from nearby highways. These factors resulted in elevated total carcinogenic risk (TCR) for Ni, Cr, and As. This study highlights soil contamination and associated health risks at the glass factory, emphasizing the need for environmental monitoring and management.