Chongqing Key Laboratory of Materials Surface & Interface Science, Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing, China
Prof. Dr. Tao Han
Chongqing Key Laboratory of Materials Surface & Interface Science, Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Chongqing, China
Light plays a vital role on the growth and development of plant. On the base of white light with high color rendering to the benefit of human survival and life, we proposed to improve “color rendering” of LED lighting for accelerating the growth of lettuce. Seven spectral LED lights were adopted to irradiate the lettuces under 150 μmol·m−2·s−1 for a 16 hd−1 photoperiod. The leaf area and number profiles, plant biomass, and photosynthetic rate under the as-prepared LED light treatments were investigated. We let the absorption spectrum of fresh leaf be the emission spectrum of ideal light and then evaluate the “color rendering” of as-prepared LED lights by the Pearson product-moment correlation coefficient and CIE chromaticity coordinates. Under the irradiation of red-yellow-blue light with high correlation coefficient of 0.587, the dry weights and leaf growth rate are 2–3 times as high as the sharp red-blue light. The optimized LED light for lettuce growth can be presumed to be limited to the angle (about 75°) between the vectors passed through the ideal light in the CIE chromaticity coordinates. These findings open up a new idea to assess and find the optimized LED light for plant growth.
Non-precious metal-based electrocatalysts with high activity and stability for efficient hydrogen evolution reactions are of critical importance for low-cost and large-scale water splitting. In this work, Mo2C–Mo3C2 heteronanowires with significantly enhanced catalytic performance are constructed from an MoAn precursor via an accurate phase transition process. The structure disordering and surface carbon shell of Mo2C–Mo3C2 heteronanowires can be precisely regulated, resulting in an enlarged surface area and a defect-rich catalytic surface. Density functional theory calculations are used to identify the effect of the defective sites and carbon shell on the free energy for hydrogen adsorption in hydrogen evolution. Meanwhile, the synergistic effect between different phases and the introduced lattice defects of Mo2C–Mo3C2 are considered to enhance the HER catalytic performance. The designed catalyst exhibits optimal electrocatalytic activity in both acidic and alkaline media: low overpotentials of 134 and 116 mV at 10 mA cm−2, a small Tafel slope of 64 mV dec−1, and a long-term stability for 5000 cycles. This work will provide new insights into the design of high-efficiency HER catalysts via interfacial engineering at the nanoscale for commercial water splitting.