Nikolay Mchedlov-Petrossyan

Prof. Dr. Nikolay Mchedlov-Petrossyan

Department of Physical Chemistry, V. N. Karazin Kharkiv National University, 61022 Kharkiv, Ukraine

Research Focus & Metrics

Academic Career Length

42Years (1985-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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24 April 2013 in Chemical Reviews
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Journal Article
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Nikolay Mchedlov-PetrossyanNikolay Mchedlov-Petrossyan
Nikolay Mchedlov-Petrossyan

1 January 1997 in Journal of the Chemical Society, Faraday Transactions
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Nikolay Mchedlov-PetrossyanNikolay Mchedlov-Petrossyan
Nikolay Mchedlov-Petrossyan
VKVladimir K. Klochkov
Vladimir K. Klochkov
GAGrigoriy V. Andrievsky
Grigoriy V. Andrievsky
The ultramicroheterogeneous dispersion of buckminsterfullerene, C60, in water was found to be a typical hydrophobic colloidal system. The studied sol was polydisperse (d from several nanometers to ca. 200 nm), with negatively charged surfaces of the particles. The coagulation by inorganic electrolytes occurs in accordance with the Schulze–Hardy rule; the reciprocal coagulation points for counter-ion charges z = 1, 2 and 3 are related as ≈1:20:1500. The results are discussed in terms of the Derjaguin–Landau–Verwey–Overbeek theory. In the case of organic electrolytes, including colloidal cationic surfactants, their coagulation points decrease with increasing hydrophobicity and surface activity of the cations. An excess of cetyltrimethylammonium bromide stabilises the fullerene dispersion. The coagulating action of the tetrabutylammonium ion depends on the nature of the co-ion. Polyvinyl pyrrolidone and sodium dodecyl sulfate protect the C60 sol from coagulation.

1 March 2004 in Russian Journal of Applied Chemistry
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Nikolay Mchedlov-PetrossyanNikolay Mchedlov-Petrossyan
Nikolay Mchedlov-Petrossyan
YKYu. V. Kholin
Yu. V. Kholin

24 June 2003 in Journal of Physical Organic Chemistry
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Nikolay Mchedlov-PetrossyanNikolay Mchedlov-Petrossyan
Nikolay Mchedlov-Petrossyan
VKValentina I. Kukhtik
Valentina I. Kukhtik
VBVasiliy D. Bezugliy
Vasiliy D. Bezugliy

1 January 2008 in Pure and Applied Chemistry
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Nikolay Mchedlov-PetrossyanNikolay Mchedlov-Petrossyan
Nikolay Mchedlov-Petrossyan
The so-called apparent ionization constants of various acids (mainly indicator dyes) in versatile organized solutions are analyzed. Aqueous micellar solutions of colloidal surfactants and related lyophilic colloidal systems display a strongdifferentiating influenceon the acidic strength of indicators located in the dispersed pseudophase, i.e., non-uniform changes of pKaon going from water to the given system. This concept allows the influence of such media on acid-base properties of dissolved reagents to be rationalized. It is demonstrated that the differentiating phenomenon is the main reason for limitation of the common electrostatic model of acid-base interactions, and is the principal hindrance to exact evaluations of the interfacial electrical potentials of ionic micelles by means of acid-base indicators. Salt effects, i.e., the influence of supporting electrolytes on the apparent ionization constants of acid-base indicators in the Stern region of ionic micelles, are considered. These salt effects can be conventionally divided into two kinds, namely,general(normal) andspecial(specific) effects. While the first type adds up to screening of the surface charge, the second one consists in micellar transitions caused by hydrophobic counterions.

1 May 2003 in Journal of Fluorescence
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Nikolay Mchedlov-PetrossyanNikolay Mchedlov-Petrossyan
Nikolay Mchedlov-Petrossyan
NVN. A. Vodolazkaya
N. A. Vodolazkaya
ADAndrey O. Doroshenko
Andrey O. Doroshenko