Oxygen transport membranes made of Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) were manufactured by tape casting and co-firing. The disk-shaped membranes consisted of a top gastight layer (70 mu m thick) and a porous substrate (830 mu m thick) with 34% open porosity. The variation of the permeation operation conditions allowed (i) the identification of the different limitations steps in the permeation process, i.e., bulk oxygen ion diffusion, catalytic surface exchange and gas phase diffusion in the membrane compartments and porous substrate, and (ii) the ultimate optimization of the oxygen flux. The variables considered in the systematic permeation study included the inlet gas flow rate of the sweep and air feed, the temperature and the nature of the oxygen feed gas (air or pure oxygen). Moreover, the influence of the deposition of a catalytic activation layer (17 mu m thick) made of BSCF on top of the thin gastight layer was investigated. As a result of this parametric study, unpreceded oxygen flux values were achieved, i.e., a maximum flux of 67.7 ml(STP) min(-1) cm(-2) was obtained at 1000 degrees C using pure oxygen as the feed and argon as the sweep, while a flux of 12.2 ml(STP) min(-1) cm(-2) at 1000 degrees C was obtained when air was used as the feed. (C) 2011 Elsevier BM. All rights reserved

Ion-conducting ceramic membrane reactors offer an opportunity to combine membrane separation processes directly with chemical reactions, leading to process intensification and, hence, benefits with regard to efficiency. Current research activities focus on membrane reactors due to their high intrinsic efficiency and great potential for the production of a large variety of commodity chemicals, energy carriers, and synthetic fuels. This includes the reduction of CO2 emissions and the utilisation of CO2.In this review, different concepts and principles of membrane reactor operation are presented followed by a comprehensive overview and discussion of different application cases. These applications are clustered according to the targeted products. The article discusses and evaluates the potential of the different concepts from the authors’ current perspective. We have not undertaken a ranking with respect to cost efficiency, process efficiency and applicability since the development levels are very different and in general at very low technology readiness levels (TRLs). However, the demonstration of one (or a few) membrane reactors at a commercially relevant size and price is urgently required in order to initiate more focussed research and development.The present review of membrane reactors aims to provide a broad overview of ongoing research activities regarding ceramic ion-conducting membrane reactors within the last ten years in the light of sustainable energy and chemical production