Volatile organic compounds (VOCs) in cooking oil fumes need to be efficiently removed due to the significant damage they cause to the environment and human health. This review discusses the emission characteristics, which are influenced by different cooking temperatures, cooking oils, and cuisines. Then, various cooking oil fume purification methods are mainly classified into physical capture, chemical decomposition, and combination methods. VOCs removal rate, system operability, secondary pollution, application area, and cost are compared. The catalytic combustion method was found to have the advantages of high VOC removal efficiency, environmental protection, and low cost. Therefore, the last part of this review focuses on the research progress of the catalytic combustion method and summarizes its mechanisms and catalysts. The Marse-van Krevelen (MVK), Langmuir-Hinshelwood (L-H), and Eley-Rideal (E-R) mechanisms are analyzed. Noble metal and non-noble metal catalysts are commonly used. The former showed excellent activity at low temperatures due to its strong adsorption and electron transfer abilities, but the high price limits its application. The transition metals primarily comprise the latter, including single metal and composite metal catalysts. Compared to single metal catalysts, the interaction between metals in composite metal catalysts can further enhance the catalytic performance.

Biomass occupies a significant proportion of municipal solid waste. For the high-value processing of waste biomass, a hydrothermal-carbonization method was chosen because of the advantages of effective and mild conditions. Four typical types of waste biomass (banana peel, mangosteen peel, orange peel, and pomelo peel) were used in this work to prepare high-value carbon aerogels (CA) via hydrothermal-carbonization treatment for cracking ethanol. Four kinds of CA all had good performances in the ethanol cracking reaction and improved the yield of H₂ from 21 wt% to about 40 wt%. The banana peel-based carbon aerogel (BPCA) showed the best performance in the reaction; it cracked ethanol and obtained 41.86 wt% of H₂. The mechanism of ethanol cracking by CA was revealed: On one hand, the self-cracking of ethanol was improved due to the extension of residence time, which benefited from the abundant pores in CA. On the other hand, the heterogeneous reaction occurred on the surface of CA where the inorganic components, mainly Ca, Mg, and K, can promote the bond-breaking and reorganization in ethanol. The CO₂ in byproducts was also fixed by Ca and Mg, improving the positive cracking reaction.

Waste tire (WT) can be heat-treated to be high-quality sulfur self-doped char via pyrolysis and K₂FeO₄-assisted activation processes. This work aimed at further studying the activation mechanisms based on the char structures evolution by operando experimental method. Activation treatment process (from 50 °C to 800 °C and then held for 3 h) was divided into six typical stages (S1–S6) and consisted of carbonization process (S1–S4) and effective activation process (S4–S6). During the carbonization process, the specific capacitance only increased from 0.2 F/g to 12.4 F/g, aromatic ring systems and alkyl-aryl C-C bonds generated, S 2p_3/2 (sulphide bridge) was mainly gradually consumed. During the effective activation process, the specific capacitance hugely increased from 12.4 F/g to 112.5 F/g, aromatic ring systems and alkyl-aryl C-C bonds turned to ordered graphitic char. The pores massively generated from S4 to S5, while micropores partly formed to larger and mesopores+macropores fractionally converting to smaller from S5 to S6. Besides, both S 2p_3/2 and S 2p_5/2 (sulphone bridge) were enriched after S5. Furthermore, the key structural parameters for huge improvement of specific capacitance were found and it further revealed that mesopores+macropores possessed stronger promotion effect than micropores and S 2p_3/2 was more beneficial than S 2p_5/2.

Phenolic resin plastic is mainly composed of phenolic resin and pyrolysis is often used to perform the important task of treating it. While there are large quantities of char generating, the char can be graphitized for upgrading under Ni-Zn-B catalytic effect. Pore structure is an important index for evaluating graphitic carbon. In this study, the phenolic resin char was graphitized with Ni-Zn-B at low temperature based on orthogonal rules (graphitization temperature: 1300 °C, 1400 °C, 1500 °C; retention time: 60 min, 120 min, 180 min; catalyst additive ratio: 5%, 10%, 15%), and their pore structures were determined by N₂ adsorption and desorption method. The graphitized phenolic resin chars were porous carbon materials whose specific surface areas were commonly between 110 to 160 m²/g; they also mainly consisted of wholly equivalent micropores and mesopores. The effects of the graphitization conditions on pore structures of GPRCs were analyzed; this revealed that the increase in graphitization temperature destroyed micropores to form mesopores, with a longer retention time leading to the production of small quantities of micropores and mesopores, some micropore spaces were occupied and mesopore skeletons were destroyed to from large pores with more Ni-Zn-B addition. The correlation models of the pore structures and reaction parameters were built; it was found that the multiple linear regression model showed an advantage in predicting micropore structures and the built artificial neural network model was better at predicting the total pore and mesopore.

Elemental mercury (Hg⁰) removal in coal combustion flue-gas over commercial V-based SCR catalysts is still limited by insufficient low-temperature activity and the complex interference of gas components. In this work, V₂O₅/TiO₂, V₂O₅⁻MoO₃/TiO₂, and V₂O₅⁻MoS₂/TiO₂ catalysts were comparatively investigated for Hg⁰ removal under simulated coal combustion flue-gas conditions. Among them, V₂O₅⁻MoS₂/TiO₂ exhibited the best performance over the whole temperature window of 200–400 °C, reaching a Hg⁰ removal efficiency of 73.3% at 200 °C, which was markedly higher than those of V₂O₅/TiO₂ and V₂O₅⁻MoO₃/TiO₂. Under multicomponent SCR atmospheres in coal-fired plants, the catalyst also showed the highest Hg⁰ oxidation efficiency of 72.9%, indicating that MoS₂ modification was more effective than oxide promotion in enhancing low-temperature mercury removal. XRD and FT-IR results showed that MoS₂ and vanadia were successfully incorporated onto TiO₂ as dispersed surface phases, while the MoS₂-modified catalyst exhibited a distinct and persistent terminal V=O feature, implying the formation of a coupled Mo-S-V interfacial environment. H₂-TPR and NH₃-TPD demonstrated that MoS₂ modification simultaneously stabilized the redox structure and moderated the surface acidity, suppressing excessively strong NH₃ retention while maintaining a tunable oxidation-active surface. XPS analysis further revealed atmosphere-dependent redistribution of O_α/O_β species, sulfur oxidation to SO₃²⁻/SO₄²⁻ species, and dynamic V⁵⁺/V⁴⁺ interconversion, confirming that MoS₂ acted not only as a sulfur-containing component but also as an interfacial electronic regulator. Post-reaction Hg 4f XPS showed that retained mercury mainly existed as Hg²⁺ species, while Hg-TPD indicated that MoS₂ modification provided a more diverse and thermally stable mercury-binding environment. These results demonstrate that Hg⁰ removal over V₂O₅⁻MoS₂/TiO₂ proceeds through oxidation-retention coupling rather than simple oxidation alone. The enhanced performance originates from the synergistic effects of active oxygen migration, vanadium redox cycling, sulfur-assisted stabilization, and interfacial Mo-S-V electronic coupling. This work provides a promising strategy for designing multifunctional SCR catalysts in coal-fired plants for efficient Hg⁰ control under practical coal combustion flue-gas conditions.