In this research, structural, magnetic properties and photocatalytic activity of cobalt ferrite spinel (CoFe2O4) nanoparticles were studied. The samples were characterized by X-ray powder diffraction (XRD), energy dispersive X-ray (EDX), scanning electron microscopy (SEM), transmission electronic microscopy (TEM), Brunauer–Emmett–Teller (BET), Fourier transform infrared spectroscopy (FTIR), and UV-visible diffused reflectance spectroscopy (DRS) analysis. The XRD analysis revealed the formation of the single-phase CoFe2O4 with a cubic structure that is annealed at 500–700 °C in 3 h. The optical band gap energy for CoFe2O4 was determined to be in the range of 1.57–2.03 eV. The effect on the magnetic properties of cobalt ferrites was analyzed by using a vibrating sample magnetometer (VSM). The particle size and the saturation magnetization of cobalt ferrite nanoparticles increased with increasing annealing temperature. The photocatalytic activity of CoFe2O4 nanoparticles was investigated by using rhodamine B dye under visible light. The decomposition of rhodamine B reached 90.6% after 270 min lighting with the presence of H2O2 and CF500 sample.
1 February 2022 in Environmental Technology & Innovation
In this study, nanocrystalline ZnNdxFe2−xO4 ferrites with x = 0.0, 0.01, 0.03 and 0.05 were fabricated and used as a catalyst for dye removal potential. The effect of Nd3+ ions substitution on the structural, optical and photo-Fenton activity of ZnNdxFe2−xO4 has been investigated. The addition of Nd3+ ions caused a decrease in the grain size of ferrites, the reduction of the optical bandgap energies and thus could be well exploited for the catalytic study. The photocatalytic activity of the ferrite samples was evaluated by the degradation of Rhodamine B (RhB) in the presence of H2O2 under visible light radiation. The results indicated that the ZnNdxFe2−xO4 samples exhibited higher removal efficiencies than the pure ZnFe2O4 ferrites. The highest degradation efficiency was 98.00%, attained after 210 min using the ZnNd0.03Fe1.97O4 sample. The enhanced photocatalytic activity of the ZnFe2O4 doped with Nd3+ is explained due to the efficient separation mechanism of photoinduced electron and holes. The effect of various factors (H2O2 oxidant concentration and catalyst loading) on the degradation of RhB dye was clarified.
In this study, we adopted the solution combustion method to synthesize magnesium ferrite (MgFe2O4) using urea as the fuel. Various techniques including TGA, XRD, SEM, TEM, FTIR, UV-Vis DRS, and EDS were employed to characterize the synthesized MgFe2O4 nanoparticles. The XRD analysis revealed that single-phase MgFe2O4 was formed at a calcination temperature of at 500–600°C for 3 hours in the absence of an intermediate phase. TEM analysis also revealed the formation of monodisperse magnesium ferrite nanoparticles, averaged at 30 nm in size. The photocatalytic activity of the synthesized MgFe2O4 nanoparticles against methylene blue dye under visible light was investigated, showing the efficiency of 89.73% after 240 minutes of light irradiation with the presence of H2O2.
Many organic dyes including rhodamine B are persistent or degraded slowly, leading to long-term retention in the aquatic environment. Here, NiFe2O4/g-C3N4 was synthesized for the photocatalytic degradation of rhodamine B dye efficiently.
Doping of neodymium ions into CoFe 2 O 4 nanoparticles significantly boosted the photocatalytic activity of CoNd x Fe
2−
x O 4 for the degradation of Rhodamine B dye. Up to 94.7% of dye was degraded under CoNd 0.05 Fe 1.95 O 4 /H 2 O 2 /visible-light system.