A novel copper(II) phthalocyanine (CuPc)-modified multiwalled carbon nanotube-based electrode was prepared for the sensitive electrochemical detection of bisphenol A, by the modification of a pencil graphite electrode via the adsorption method. The synthesized novel CuPc was characterized by spectroscopic methods and the electrodes were characterized by electrochemical, spectroscopic and microscopic methods. The limit of detection (LOD, S/N = 3) was calculated as 0.0189 μM for bisphenol A. The experimental parameters such as pH and adsorption time were optimized for the electrochemical detection of bisphenol A. The detection was done in real samples, with a high recovery value (>98%), indicating the useful application of modified electrodes as electrochemical sensors for bisphenol A. The electrodes showed excellent repeatability and stability in the differential pulse voltammetric detection of bisphenol A. The prepared novel sensor can be used for the detection of bisphenol A in many environmental analyses due to its simplicity, low cost, environmental friendliness and high sensitivity.
Summary: The applications of electrophoretic deposition (EPD) to the development of electrochemical energy storage (EES) devices such as batteries and supercapacitors are reviewed. A discussion on the selection of parameters for optimizing EPD electrode performance, such as light‐directed EPD, co‐deposition of active materials such as metal oxides and materials manufactured with high porosity and fibrous properties is highlighted. Additionally, means for overcoming obstacles in the improvement of the mechanical properties, conductivity and surface area of EES materials are discussed. The exceptional benefits of EPD such as low cost, small processing time, simple apparatus requirements, homogeneous coatings, binder‐free deposits and selective modification associated with thickness and mass loadings leading to effective EES electrode materials are highlighted. Finally, EPD processes have evolved as modern manufacturing tools to produce technologically improved solid electrolytes and separators for lithium‐ion and/or sodium‐ion batteries, and further research and development programmes are encouraged towards industrialisation.
21 June 2020 in International Journal of Energy Research