This study presents a study of nanoclay-surfactant-stabilized foam to improve the oil recovery of steam flooding in offshore heavy oil reservoirs. The foam stability and thermal resistance studies were first performed to investigate the influence of nanoclay on the stability and thermal resistance properties of the foam system. Then, the sandpack flooding tests were conducted for investigating the resistance factor and displacement abilities by nanoclay-surfactant-stabilized foam. The results showed that the nanoclay-surfactant-stabilized foam has excellent foaming ability and foam stability at 300 °C, which can be used in steam flooding for offshore heavy oil reservoirs. The resistance factor is greater than 30 at 300 °C when the gas–liquid ratio ranges from 1 to 3, which indicated that the nanoclay-surfactant-stabilized foam has good performance of thermal resistance and plugging effect. The heterogeneous sandpack flooding test showed that the nanoclay-surfactant-stabilized foam can effectively divert the steam into the low-permeability area and improve the sweep efficiency, thus improving heavy oil recovery of steam flooding. Therefore, the nanoclay-surfactant-stabilized foam flooding has a great potential for improving oil recovery of steam flooding in offshore heavy oil reservoirs.

Cyclic steam stimulation (CSS) is a typical enhanced oil recovery method for heavy oil reservoirs. In this paper, a new model for the productivity of a CSS well in multilayer heavy oil reservoirs is proposed. First, for the steam volume of each formation layer, it is proposed that the total steam injection volume will be split by the formation factor (Kh) for the commingled steam injection mode. Then, based on the equivalent flow resistance principle, the productivity model can be derived. In this model, the heavy oil reservoir is composed of a cold zone, a hot water zone, and a steam zone. Next, using the energy conservation law, the equivalent heating radius can be calculated with the consideration of the steam overlay. Simultaneously, a correlation between the threshold pressure gradient (TPG) and oil mobility is also applied for the productivity formula in the cold zone and the hot water zone. Afterward, this model is validated by comparing the simulation results with the results of an actual CNOOC CSS well. A good agreement is observed, and the relative error of the cumulative oil production is about 2.20%. The sensitivity analysis results indicate that the effect of the bottom hole pressure is the most significant, followed by the TPG, and the effect of the steam overlay is relatively slight. The formation factor can affect the splitting of the steam volume in each layer; thus, the oil production rate will be impacted. The proposed mathematical model in this paper provides an effective method for the prediction of preliminary productivity of a CSS well in a multilayer heavy oil reservoir.

The desorption of heavy oil is one of the important indicators affecting the development efficiency of the remaining oil in nanopores. However, the study of the adsorption and diffusion mechanisms of heavy oil molecules in nanopores remains scarce. In this work, the influences of temperature on the adsorption and diffusion properties of the heavy oil four-fractions in quartz nanopore have been investigated via molecular dynamics simulations. Our results show that the heavy oil molecules will form a denser multilayer adsorption oil layer on the nanopore surface, and high temperature can alter the adsorption behaviors of the heavy oil four-fractions. As the temperature increases, the saturate molecules are desorbed from the nanopore surfaces, but the aromatic, resin, and asphaltene molecules maintain a tendency to aggregate towards the nanopore surface. In particular, the agglomeration behaviors of most saturate, aromatic and asphaltene molecules in nanopore can be suppressed by the confined space compared with the heavy oil molecules in oil droplet. In addition, the influence of temperature on the movement of heavy oil molecules in nanopore decreases compared with the oil molecules in a heavy oil droplet due to the confined space and adsorption effect. Interestingly, there is a competition phenomenon between the adsorption and diffusion of aromatic, resin, and asphaltene molecules in the nanopore, resulting in different adsorption behaviors with the increase in temperature. The results obtained in this paper will provide molecular-level theoretical guidance for understanding the adsorption and desorption mechanisms of heavy oil in nanopores.

A series of kinetics and combustion tube experiments were conducted to investigate the combustion characteristics and performance of in situ combustion (ISC) process for offshore heavy oils. Then, simulation studies were carried out to evaluate the performance of the ISC process in a typical offshore heavy oil reservoir. The results showed that higher heating rates resulted in a shift in the thermogravimetry curves and an increase in the weight loss rate. The oil recovery, oxygen utilization, and air/oil ratio of the combustion experiment are 95.1%, 97.27%, and 547.78 m³/t, respectively. This research will provide technical support for ISC applications in offshore heavy oil reservoirs