Development of acid-stable electrocatalysts with low overpotential for oxygen evolution reaction (OER) is a major challenge to produce hydrogen directly from water. We report in this paper a pyrochlore yttrium ruthenate (Y₂Ru₂O_7−δ) electrocatalyst that has significantly enhanced performance toward OER in acid media over the best-known catalysts, with an onset overpotential of 190 mV and high stability in 0.1 M perchloric acid solution. X-ray absorption near-edge structure (XANES) indicates Y₂Ru₂O_7−δ electrocatalyst had a low valence state that favors the high OER activity. Density functional theory (DFT) calculation shows this pyrochlore has lower band center energy for the overlap between Ru 4d and O 2p orbitals and is therefore more stable Ru–O bond than RuO₂, highlighting the effect of yttrium on the enhancement in stability. The Y₂Ru₂O_7−δ pyrochlore is also free of expensive iridium metal and thus is a cost-effective candidate for practical applications.

When nanoparticles become small (ca. <5 nm), surface stress becomes significant and generates strain that results in a change of surface structures. In this regard, the surface lattice of nanoparticles can be engineered to create strains or other structural changes with atomic positions away from the normal lattice points. Such changes impact the electronic and catalytic properties of nanoparticles. Recently, several groups have reported the change of catalytic and electrocatalytic properties of bimetallic nanoparticles. In this tutorial review, we discuss the principles related to lattice strain and other distorted structures, and the catalytic properties of bimetallic nanostructures.