Stress redistribution and stress drop often coincide with fracture processes. The two experiments that were chosen for our b-value analysis generate failure processes with the corresponding stress drops and stress redistributions. Using acoustic emission analysis, the acoustic waves emitted from the different fracture areas are recorded. The cumulative frequency-magnitude distribution, which leads to the b-value, was originally used in seismology to characterize earthquake populations. Concerning acoustic emissions, the b-value decreases with increasing stress levels. Therefore, it was possible to determine the start of the arise of macro-cracks over time using the b-value analysis. Furthermore, a possible application in a monitoring procedure is suggested.