Today, new materials based on natural fibres have been emerging day by day to completely eradicate plastics to favour our environmental nature. In this view, the present work is based on the extraction and characterisation of the novel root fibres of the Zea mays (Zm) plant, grown by the hydroponic method. Both the dried untreated and alkali treated root fibres are investigated using a variety of structural, morphological, thermal, elemental and mechanical tests by subjecting both the samples to p-XRD, FT-IR, SEM-EDAX, TGA-DTA, CHNS and tensile strength analyses. Thermal conductivity of the untreated and treated fibres is found using Lee’s disc experiment. From p-XRD analysis, the Crystallinity Index, Percentage Crystallinity and Crystallite size of the samples are found. FT-IR studies clarify the different vibrational groups associated with the fibre samples. SEM images show that the surface roughness increases for the chemically treated samples, such that it may be effectively utilised as reinforcement for polymeric composites. The diameter of the fibre samples is found using SEM analysis. According to the EDAX spectrum, Zm fibres in both their raw and processed forms have high levels of Carbon (C) and Oxygen (O). The TGA-DTA tests revealed that the samples of natural fibre have good thermal characteristics. CHNS studies show that Carbon content is high for these samples, which is the characteristic of many natural fibres. Chemical analysis is used to ascertain the prepared samples’ chemical makeup. It reveals that both samples have significant amounts of cellulose. The density of the fibres is found to be in the range 0.3–0.6 g/cc, which is much less than any other natural fibre. Therefore, it can be used in light weight applications. From the tensile strength analysis, physical properties such as Young’s modulus and micro-fibril angle are determined. The fibres in the roots exhibit a lower tensile strength. Thus, these fibres can be used in powdered form as reinforcement for natural rubber or epoxy composites. After examining all of its properties, it could be reasonably speculated that Zea mays root fibres can be considered as an efficient reinforcement for various matrices to produce attractive bio-composites.
10 June 2023 in Journal of Materials Research and Technology
Due to the COVID-19 epidemic, biomedical waste management has overwhelmed both developed and developing nations. It is now a critical issue that has to be addressed with minimal possible adverse impact on the environment. This study introduced a technique of recycling face masks into polypropylene fibers for use in concrete. This proposed recycling process provides complete disinfection of contaminated clinical waste and offers the opportunity to transform the characteristics of an end product. Microfibers manufactured from recycled medical masks were subjected to testing. According to the results, polypropylene is the primary component of this research program. Two batches of concrete were made, one with the inclusion of masks as polypropylene fibers and another that performed as a control mix. The modified mortar was compared to the control mix in split tensile, flexure, compressive strength, and water absorption. Compressive strength was found to be improved by about 17%, and tensile strength to be increased by around 22% when mask fibers were incorporated. This research introduced a novel approach for disposing of waste masks and established the preliminary viability of upcycling trash face masks towards mortar concrete production.
16 December 2023 in Case Studies in Construction Materials
Micronized biomass silica (MBS) and ground granulated blast furnace slag (GGBS) are agro-industrial byproducts generated by incinerating of rice husk (grinding in jar mill) and blast furnaces that used produce iron, respectively. MBS accounts for 20% of the world's total paddy output of 590 million tons. These by-products (MBS and GGBS) have a high concentration of amorphous silica, which is utilized as a mineral additive in concrete. This amorphous silica interacts with hydration products, resulting in the formation of additional CSH gel. This improves concrete's strength and durability properties. Therefore, it is proven that inclusion of agro-industrial by-products in concrete helps to promote sustainable and greener development, which in turn reduces carbon footprints and waste that must be disposed of in landfills. There have been few investigations on concrete using MBS and demonstrated the great potential of employing MBS as a cement substitute or additive in normal concrete. Also, the utilization of MBS as partial replace to GGBS in geopolymer concrete (GPC) with different molarity is a novel aspect of this study. However, this study has the aim and limit to develop a high-strength eco-friendly GPC with agro-industrial byproducts (MBS and GGBS) for use in sustainable construction. The impact of incorporating MBS as a partial replacement of GGBS on compressive and split tensile strengths, sorptivity, and chloride permeability was tested up to the age of 28 days. MBS was used to replace GGBS in varying percentages in the preparation of concretes. MBS were used in concrete at 0%, 10%, 20%, and 30% replacement by weight. It was discovered that a GPC combination containing MBS 20% and the balance GGBS as the binder had the best performance in terms of its strength and durability. The compressive strengths of all GPC mixtures exceeded the intended design strength. The main findings of this study demonstrated clearly that MBS may be employed as a binder in the production of GPC.
This study emphasizes the importance of utilizing biodegradable material Butea parviflora (BP) fiber for sustainable solutions. BP fiber offers numerous ecological benefits, such as being lightweight, biodegradable, and affordable to recycle. The study examines the effects of potassium permanganate (KMnO4) treatment on BP fiber and analyzes its physical and chemical behavior using various methods, including X-ray Diffraction (XRD) analysis, tensile testing, thermogravimetric analysis, thermal conductivity, Scanning Electron Microscopy (SEM), and Fourier Transform Infrared spectroscopic (FTIR) analysis. The results demonstrate that BP fiber possesses low density (1.40 g/cc) and high cellulose content (59.4%), which fosters compatibility between the matrix and resin. XRD analysis indicates a high crystallinity index (83.47%) and crystallite size (6.4 nm), showcasing exceptional crystalline behavior. Treated fibers exhibit improved tensile strength (198 MPa) and Young’s modulus (4.40 GPa) compared to untreated fibers (tensile strength—92 MPa, tensile modulus—2.16 GPa). The Tg-DTA thermograms reveal the fiber’s thermal resistance up to 240 °C with a kinetic activation energy between 62.80–63.46 KJ/mol. Additionally, the lowered thermal conductivity (K) from Lee’s disc experiment suggests that BP fiber could be used in insulation applications. SEM photographic results display effective surface roughness for composite making, and FTIR studies reveal vibrational variations of cellulosic functional groups, which correlates with increased cellulosic behavior. Overall, the study affirms the potential of BP fiber as a reinforcing material for composite-making while emphasizing the importance of utilizing biodegradable materials for sustainability.
The most valuable components of coal fly ash are cenospheres. Cenospheres are hollow spherical particles produced during the coal-burning processes. As a result of their excellent characteristics, such as high workability, high heat resistance, low bulk density, and high strength, cenospheres can be used in the manufacturing of lightweight cement concrete. The research efforts and outcomes are to produce long-lasting cement-based lightweight concrete (LWC) composites with good mechanical properties. The novelty of this investigation is to determine the cement concrete strength when silica fume (SF) and cenospheres (CS) were used as a replacement for cement. Throughout the experiments, a consistent substitution of 12% silica fume was incorporated into cement mass. Silica is used as a micro filler and pozzolanic reactant to strengthen concrete. The concrete mixtures were tested to ensure they met the requirements of the lightweight concrete in terms of their mechanical, physical, and durability qualities. According to the findings, lightweight concrete standards were met, and environmental sustainability was improved with the use of these mix proportions. Concrete specimen’s self-weight decreases by 35% with 30% cenosphere as a replacement. The micrograph shows the lack of portlandite is filled by mullite and other alumino silicates from the cenosphere. In order to achieve sustainability in concrete manufacturing, these mixtures can be suggested for the making of structural LWC that makes use of a large volume of industrial waste while conserving cement and natural resources.