The removal of bisphenol-A (BPA) from the aqueous environment is a vital issue for public health due to its toxic effect. In this work, variable amounts of the dextran coated-magnetite doped metal–organic framework nanocomposites (MOF:Fe3O4@Dex) were successfully prepared and used as an adsorbent for the removal of BPA from aqueous solution. Firstly, dextran-coated magnetite nanoparticles (Fe3O4@Dex) were synthesized via the co-precipitation method, and then MIL-100(Fe) nanocomposites (MOF:Fe3O4@Dex), including different amounts of Fe3O4@Dex nanoparticles, were prepared by the reflux method. The obtained nanocomposites were characterized through Fourier transform infrared spectroscopy, powder X-ray diffraction, thermogravimetric analysis, scanning and transmission electron microscopy, and magnetic and surface measurements. The batch adsorption method was carried out as a function of pH, adsorbent amount, contact time, and initial BPA concentration for the removal of BPA using the MOF:Fe3O4@Dex nanocomposite. The adsorption of BPA could be completed within approximately 60 min at room temperature using 300 mg L−1, 100 mL, pH 5 BPA solution. The maximum adsorption capacity of BPA on the MOF:Fe3O4@Dex nanocomposite was calculated as 347 mg g−1, which is quite a high value compared to that of the previously reported adsorbents. After five cycles, the adsorption capacity of the MOF:Fe3O4@Dex nanocomposite was still retained at a high level. The adsorption kinetics, isotherms, and mechanisms were also investigated. All the results proved that the magnetic nanocomposite (MOF:Fe3O4@Dex) could be a potential candidate for water purification applications.
1 September 2011 in International Journal of Hydrogen Energy
Magnetic nanocomposites comprising elemental boron and vitamin C in the form of mono or bis(ascorbatoborate) complexes have been synthesized for targeted delivery/therapy applications. These nanocomposites were characterized by chemical analysis, X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), transmission electron microscopy (TEM), and magnetic measurements. Structural motifs were proposed to justify the arrangement of the complexes around the magnetic core. The nanocomposite particles showed a quasi-spherical morphology with an average size of around 10–15 nm and exhibited a superparamagnetic behavior at 300 K to qualify for potential targeted biomedical applications. The data of chemical analysis suggested that the nanocomposites contain ca. 1015 boron atoms per microgram of sample.
15 October 2018 in Journal of Thermal Analysis and Calorimetry