This article presents an overview of the reports on the doping of TiO₂ with carbon, nitrogen, and sulfur, including single, co-, and tri-doping. A comparison of the properties of the photocatalysts synthesized from various precursors of TiO₂ and C, N, or S dopants is summarized. Selected methods of synthesis of the non-metal doped TiO₂ are also described. Furthermore, the influence of the preparation conditions on the doping mode (interstitial or substitutional) with reference to various types of the modified TiO₂ is summarized. The mechanisms of photocatalysis for the different modes of the non-metal doping are also discussed. Moreover, selected applications of the non-metal doped TiO₂ photocatalysts are shown, including the removal of organic compounds from water/wastewater, air purification, production of hydrogen, lithium storage, inactivation of bacteria, or carbon dioxide reduction.

A simple wet impregnation-calcination method was used to obtain a series of novel non-metal doped TiO₂ photocatalysts. Biuret was applied as C and N source, while raw titanium dioxide derived from sulfate technology process was used as TiO₂ and S source. The influence of the modification with biuret and the effect of the atmosphere (air or argon) and temperature (500–800 °C) of calcination on the physicochemical properties and photocatalytic activity of the photocatalysts towards ketoprofen decomposition under simulated solar light was investigated. Moreover, selected photocatalysts were applied for ketoprofen photodecomposition under visible and UV irradiation. Crucial features affecting the photocatalytic activity were the anatase to rutile phase ratio, anatase crystallites size and non-metals content. The obtained photocatalysts revealed improved activity in the photocatalytic ketoprofen decomposition compared to the crude TiO₂. The best photoactivity under all irradiation types exhibited the photocatalyst calcined in the air atmosphere at 600 °C, composed of 96.4% of anatase with 23 nm crystallites, and containing 0.11 wt% of C, 0.05 wt% of N and 0.77 wt% of S.