Polymer microspheres (PMs) are used as a new material to recover residual oil left in unswept oil areas after secondary recovery methods. The fact that the PMs plug the macropores causes the flow direction of the injection fluid to be transferred from macropores to micropores. In order to investigate the plugging and profile control mechanisms of PMs in reservoirs, four kinds of PMs with different particle sizes and four kinds of artificial cores with different permeability were selected for flooding tests, including plugging experiments and profile control experiments. The pore throat size distribution of cores was characterized by nuclear magnetic resonance (NMR) technology. The particle size distribution of PMs used in the experiment was characterized using a laser particle size analyzer. The results showed that there are six matching relationships existing simultaneously between pore throats and PMs based on theoretical analysis, which are completely plugging, single plugging, bridge plugging, smooth passing, deposition, and deformable passing. A key principle for optimizing PMs in profile control is that the particle size of the selected PMs can enter the high permeability layer well, but it is difficult for it to enter the low permeability layer. The results of this paper provide a theoretical basis for the optimal particle size of PMs during the oil field profile control process.

In the waterflooding development of fractured ultra-low permeability reservoirs, the heterogeneity is becoming increasingly serious. The development of large fracture channels leads to serious water channelling and low recovery, and the effect of conventional profile control is not ideal. This paper proposed gel foam composite profile control and flooding technology to solve the above problems. Herein, the new intelligent gel and foaming agent systems were optimized through laboratory experiments, and their performance was evaluated. The new intelligent gel system has the characteristics of low viscosity, easy preparation, good injection, slow cross-linking, high strength, and long-term effectiveness. The injection parameters were optimized, and the indoor injection scheme was formulated, that is, the optimal injection volumes of gel and foam slugs were 0.3 and 0.6 PV, respectively. The injection sequence of composite slugs was to inject gel slugs first, then foam slugs. The injection mode of air foam slugs was multiple rounds of small slug injection. The final recovery rate in the indoor dual tube oil displacement experiment reached 35.01%, increasing by 23.69%. Furthermore, an oil output increase of 899 t and an average water cut decrease of 5% were acquired in the oil field test. It shows that the injection scheme can effectively improve oil recovery. The gel foam compound profile control and flooding technology herein has good adaptability in similar reservoirs and has good promotion prospects.

Differences in the properties of clay minerals cause formation damage under the condition of thermal production in heavy-oil reservoirs; asphaltenes adsorbed on clay minerals exacerbate the formation damage. The purpose of the present study was to reveal the variation in clay minerals and the adsorption behavior of asphaltenes on clay mineral surfaces under thermal recovery conditions. Volume changes and transformations of typical clay minerals were studied under various conditions (80 and 180°C, pH 9 and 11, aqueous and oven-dry conditions). On this basis, the adsorption behavior and mechanism of asphaltenes on the surfaces of clay minerals in various simulated conditions were investigated. The adsorption mechanism was revealed using kinetics and isothermal adsorption models. The results showed that the volume of montmorillonite expanded by up to 159.13% after water–rock interaction at 180°C with pH 11; meanwhile, the conversion rates of kaolinite and illite to montmorillonite were 6.6 and 7.8%, respectively. The water–rock interaction intensified the volume changes and transformations of clay minerals under thermal conditions. The amounts of asphaltene adsorbed on clay minerals at 180°C were greater than those at 80°C. The adsorption process of asphaltenes was inhibited under aqueous conditions. The abilities of the constituent minerals to bind asphaltenes was in order: montmorillonite > chlorite > kaolinite > illite > quartz sand. The adsorption process of asphaltenes yielded high coefficients of regression with both the Freundlich and Langmuir models under oven-dry (>0.99) and aqueous (>0.98) conditions. At 180°C under aqueous conditions, the water film significantly inhibited the adsorption of asphaltene on the clay minerals. The adsorption process of asphaltenes, therefore, could be regarded as the adsorption occurring at lower concentrations under oven-dry conditions.

With the introduction of China’s “dual carbon” goals, CO₂ is increasingly valued as a resource and is being utilized in unconventional oil and gas development. Its application in fracturing operations shows promising prospects, enabling efficient extraction of oil and gas while facilitating carbon sequestration. The process of reservoir stimulation using CO₂ fracturing is complex, involving coupled phenomena such as temperature variations, fluid behavior, and rock mechanics. Currently, numerous scholars have conducted fracturing experiments to explore the mechanisms of supercritical CO₂ (SC-CO₂)-induced fractures in relatively deep formations. However, there is relatively limited numerical simulation research on the coupling processes involved in CO₂ fracturing. Some simulation studies have simplified reservoir and operational parameters, indicating a need for further exploration into the multi-field coupling mechanisms of CO₂ fracturing. In this study, a coupled thermo-hydro-mechanical fracturing model considering the CO₂ properties and heat transfer characteristics was developed using the phase field method. The multi-field coupling characteristics of hydraulic fracturing with water and SC-CO₂ are compared, and the effects of different geological parameters (such as in situ stress) and engineering parameters (such as the injection rate) on fracturing performance in tight reservoirs were investigated. The simulation results validate the conclusion that CO₂, especially in its supercritical state, effectively reduces reservoir breakdown pressures and induces relatively complex fractures compared with water fracturing. During CO₂ injection, heat transfer between the fluid and rock creates a thermal transition zone near the wellbore, beyond which the reservoir temperature remains relatively unchanged. Larger temperature differentials between the injected CO₂ fluid and the formation result in more complicated fracture patterns due to thermal stress effects. With a CO₂ injection, the displacement field of the formation deviated asymmetrically and changed abruptly when the fracture formed. As the in situ stress difference increased, the morphology of the SC-CO₂-induced fractures tended to become simpler, and conversely, the fracture presented a complicated distribution. Furthermore, with an increasing injection rate of CO₂, the fractures exhibited a greater width and extended over longer distances, which are more conducive to reservoir volumetric enhancement. The findings of this study validate the authenticity of previous experimental results, and it analyzed fracture evolution through the multi-field coupling process of CO₂ fracturing, thereby enhancing theoretical understanding and laying a foundational basis for the application of this technology.