Single-atom catalysts provide an effective approach to reduce the amount of precious metals meanwhile maintain their catalytic activity. However, the sluggish activity of the catalysts for alkaline water dissociation has hampered advances in highly efficient hydrogen production. Herein, we develop a single-atom platinum immobilized NiO/Ni heterostructure (Pt_SA-NiO/Ni) as an alkaline hydrogen evolution catalyst. It is found that Pt single atom coupled with NiO/Ni heterostructure enables the tunable binding abilities of hydroxyl ions (OH*) and hydrogen (H*), which efficiently tailors the water dissociation energy and promotes the H* conversion for accelerating alkaline hydrogen evolution reaction. A further enhancement is achieved by constructing Pt_SA-NiO/Ni nanosheets on Ag nanowires to form a hierarchical three-dimensional morphology. Consequently, the fabricated Pt_SA-NiO/Ni catalyst displays high alkaline hydrogen evolution performances with a quite high mass activity of 20.6 A mg⁻¹ for Pt at the overpotential of 100 mV, significantly outperforming the reported catalysts.

A hybrid catalyst based on single-atom Pt anchored Co(OH)₂ nanosheets growing on a Ag nanowire network with high intrinsic activity is developed for an efficient hydrogen evolution reaction.

An Ir single atom catalyst supported by oxygen vacancy-modulated CoNiO ₂ is constructed (Ir _SA -V _O -CoNiO ₂ ), in which the oxygen vacancy coupling with Ir atoms in CoNiO ₂ facilitates the participation of lattice oxygens in OER.