The mineralization within the North China Craton (NCC) is intricately linked to Mesozoic large-scale extension in eastern China and is a consequence of a unified geodynamic tectonic background. Despite previous attempts to elucidate the relationship between large-scale mineralization and magmatic activity in the NCC, a lack of systematic research has hindered the identification of connections among deposits with inconsistent metallogenic ages. This study focuses on the coal measures of the Huanghebei Coalfield (HHBC) in western Shandong, presenting a regional magmatic–hydrothermal metallogenic system with a genetic connection. It delves into the intricate interplay between the multi-mineral enrichment mechanism, metallogenic regularity, and the NCC’s destruction. The findings reveal that: (1) Various stages of magmatic intrusion during the Yanshanian period significantly influenced the Late Paleozoic coal measures in the HHBC. The coal measures exhibit distinct ranks, ranging from medium-rank bituminous C to A and high-rank anthracite C, resulting in noticeable differences in gas generation among different coal ranks. The shale between the coal seams C5 and C7 emerges as excellent with a good hydrocarbon-generating capacity during the middle-maturity stage. (2) The “Intrusion along the rock layer type” proves most conducive to shale gas enrichment, while the “laccolith type” is more favorable for shale gas enrichment compared to “dike type” intrusions, which have a limited impact on shale gas enrichment. (3) The mineralization process of CBM, shale gas, and iron ore is influenced by Yanshanian-period magma. The enrichment degree of CBM and shale gas exhibits an inverse correlation with the distance from the magmatic intrusion. Iron deposits demonstrate a close association with the magmatic intrusion, with enhanced enrichment along the rock layer. The results indicate that the destruction of the NCC triggered intense metasomatism in the deep cratonic fluids, serving as the primary driving mechanism for large-scale mineralization during the Yanshanian period. Magmatic intrusions bring hydrothermal fluids conducive to mineralization, and the heat release from these intrusions promotes thermal evolution, hydrocarbon generation, and the enrichment of organic-rich strata.

The Jinqingding gold deposit, characterized as an extra-large quartz-vein-type deposit, is located in the middle of the Mouping–Rushan metallogenic belt in the Jiaodong Peninsula, and there is still controversy over its sources of ore-forming materials and fluids. This paper divides the mineralization of Jinqinding gold deposits into four stages, based on a field geological investigation and indoor petrographic observations: (1) coarse-grained pyrite–quartz stage, (2) quartz–fine-grained pyrite stage, (3) quartz–polymetallic sulfide stage, and (4) quartz–carbonate stage. The quartz fluid inclusions showed δD values of −96.0 to −81.8‰ and δO_V-SMOW values of 0.70 to 6.32‰, indicating that the ore-forming fluids were mainly magmatic water, with some metamorphic water and atmospheric precipitation. The in situ δ³⁴S values in different subzones of the pyrites of the Jinqingding gold deposit range from 6.69 to 10.86‰. The δ³⁴S value range of the Jinqingding gold deposit is basically consistent with the contemporaneous intermediate–basic dikes in the region, suggesting a shared material source. In situ LA-ICP-MS geochemical analyses of the pyrites show large variations of Co/Ni ratios (0.21 to 99.5), which suggest a hydrothermal origin for the gold deposit. We infer that the ore-forming fluid of the Jinqingding gold deposit originated from the magma from the upper mantle and the mantle–crust transition zone.

The North China Craton hosts abundant skarn iron resources, yet the regional large-scale mineralization mechanism remains incompletely understood. The Litun deposit is a newly discovered skarn iron deposit in the North China Craton. Integrated field geological investigations, petrographic observations, fluid inclusion microthermometry and stable isotope geochemistry are applied to constrain evaporite contributions to metallogenic processes. Four mineralization stages are identified: skarn, oxide, sulfide, and carbonate. Early skarn-stage fluids are iron-rich magmatic hydrothermal fluids with high temperatures (498 to >550 °C), high salinities (18.6 to 59.4 wt% NaCl eqv.), and magmatic δ¹⁸O values of 8.3 to 10.8‰. Subsequent oxide to late carbonate stages record continuous infiltration of meteoric water, supported by H–O isotopic trends of rising meteoric water proportions. Pyrite from the magnetite ores has δ³⁴S_V-CDT values between 12.0 and 15.0‰, significantly higher than those of pyrite in the Litun diorite (−0.8 to 1.1‰), indicating the contributions of sulfur from evaporites (δ³⁴S_V-CDT 26.9 to 28.6‰) in the mineralization process. Moreover, vein pyrite formed in later stages displays even higher δ³⁴S values (17.3 to 20.9‰), demonstrating progressive enrichment of evaporite-derived sulfur as hydrothermal activity evolves. Synchronous rises in meteoric water fraction and evaporite sulfur proportion indicate evaporites are delivered into the ore-forming system via meteoric water mixing. The mixing of meteoric water containing dissolved evaporites and iron-rich magmatic-hydrothermal fluids may be the major mechanism of magnetite precipitation in the Litun deposit.