Untreated hexamethylenetetramine (HMT) was discharged into the Tone River in the central area of Japan, and the risk management plan in the watershed area has been strengthened because HMT is the precursor of formaldehyde (FA) regulated by Japanese water supply law. The release of HMT could occur not only in steady but also in unsteady environmental conditions. In this context, no quantitative environmental risk assessments have dealt with the combined events of FA precursor outflow and natural disasters, such as a massive tsunami attack. In this study, we estimated the time course changes of HMT concentrations at the near water treatment plant (WTP) intakes due to tsunami run-up in the river after HMT discharge from facilities along the river during a massive tsunami attack, then potential ecological and health impacts were estimated. This method has a strong analytical ability to reveal the relationship between wave source and inland water run-up in consideration of 3D density flow. For ecological risk, the half maximal effective concentration (EC50) was employed. We found that HMT concentration would not reach a level of concern even after the accident. For potential health risk in terms of the possible maximum inlet concentration of HMT at the WTP, the FA formation amount was 5.3 × 10−2 mg/L, which was below the water quality standard.
1 January 2016 in Journal of Japan Society of Civil Engineers, Ser. A2 (Applied Mechanics (AM))
Tsunami run-up can transport released substances toward river drinking-water intakes. This study evaluates transport to the Kunijima intake in the Yodo River using a coupled two-dimensional horizontal–three-dimensional hydrodynamic model with tank-release, dissolved-substance transport, and density calculations. Twenty-three cases examine salinity, substance density, release location, release volume, and river-flow and operating conditions under one Nankai Trough tsunami scenario. Previously published density and release-location simulations are extended through intake-concentration analysis. A formaldehyde-based reference threshold of 0.08 mg/L provides a common comparison benchmark rather than a generic safety criterion. The substance did not reach the intake in the freshwater-like downstream-salinity case during the 36 h simulation, whereas the highest-salinity case exceeded the threshold for approximately 30 h. The density response was non-monotonic, with 1100 kg/m3 producing the highest peak among tested densities. Increasing release volume mainly increased concentration magnitude; the higher-flow condition delayed arrival and reduced the peak. Density diagnostics support salinity-related stratification, while analytical advection tests demonstrate resolution-dependent numerical spreading. The results support scenario-based interpretation of intake concentration responses, but absolute concentrations and exceedance durations remain conditional estimates without direct validation of the complete transport application.
1 January 2021 in Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering)