An experimental method based on the Landau-Zener model was developed to measure very small tunnel splittings in molecular clusters of eight iron atoms, which at low temperature behave like a nanomagnet with a spin ground state of S = 10. The observed oscillations of the tunnel splittings as a function of the magnetic field applied along the hard anisotropy axis are due to topological quantum interference of two tunnel paths of opposite windings. Transitions between quantum numbers M = − S and ( S − n ), with n even or odd, revealed a parity effect that is analogous to the suppression of tunneling predicted for half-integer spins. This observation is direct evidence of the topological part of the quantum spin phase (Berry phase) in a magnetic system.
19 April 2016 in Journal of the American Chemical Society
Electrical control of nuclear spin qubits: Quantum bits of information (qubits) that are based on spins of atomic nuclei are an attractive option for quantum information processing. It can sometimes be tricky to manipulate these qubits using magnetic fields directly. Thiele et al. developed a technique for electrically controlling a nuclear spin qubit in the single-molecule magnet TbPc 2 . When they hit the qubit with a microwave pulse, the microwave's electric field generated effective magnetic fields much larger than those available previously. Science , this issue p. 1135