In order to improve the performance of 17-4PH under wear conditions (e.g., gears, etc.) and reduce the cost of metal additive manufacturing, TiC needs to be added to 17-4PH to improve its wear resistance. Micron-sized TiC-reinforced 17-4PH stainless steel composites with different contents (0–15 wt%) have been prepared by fused filament fabrication 3D printing for the first time. The effects of TiC content on the structure and properties of composites were studied by XRD, SEM, and sliding wear. The obtained results show that the microstructure of TiC-reinforced 17-4PH stainless steel composites mainly consists of austenite. With the increase in TiC content, the grain size is obviously refined, and the average grain size decreases from 65.58 μm to 19.41 μm. The relative densities of the composites are maintained above 95% with the addition of TiC. The interfaces between TiC particles and the 17-4PH matrix are metallurgical bonds. The hardness of the composites increases and then decreases with increasing TiC content, and the maximum hardness (434 HV) is obtained after adding 10 wt.% of TiC content. The wear rate of the composites was reduced from 2.191 × 10⁻⁵ mm³ /(N‧m) to 0.509 × 10⁻⁵ mm³ /(N‧m), which is a 3.3-fold increase in wear resistance. The COF value declines with the addition of TiC. The reasons for the significant improvement in the composites’ performance are fine grain strengthening, solid solution strengthening, and second phase strengthening. The wear mechanisms are mainly abrasive and adhesive wear. Compared to the 10 wt% TiC composites, the 15 wt% TiC composites show limited improvement in wear resistance due to more microcracks and TiC agglomeration.

The application of superamphiphobic coatings improves the surface’s ability to repel fluids, thereby greatly enhancing its various functions, including anti-fouling, anti-corrosion, anti-icing, anti-bacterial, and self-cleaning properties. This maximizes the material’s potential for industrial applications. This work utilized the agglomeration phenomenon exhibited by nano-spherical titanium dioxide (TiO₂) particles to fabricate 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PFDTES) modified TiO₂ (TiO₂@fluoroPOS) fillers with low surface energy. This was achieved through the in-situ formation of protective armor on the surface of the agglomerates using the sol-gel method and fluorination modification. Polyvinylidene fluoride-tetrafluoropropylene (PVDF-HFP) and TiO₂@fluoroPOS fillers were combined using a spraying technique to prepare P/TiO₂@fluoroPOS coatings with superamphiphobicity. Relying on the abundance of papillae, micropores, and other tiny spaces on the surface, the coating can capture a stable air film and reject a variety of liquids. When the coatings were immersed in solutions of 2 mol/L HCl, NaCl, and NaOH for a duration of 12 h, they retained their exceptional superamphiphobic properties. Owing to the combined influence of the armor structure and the organic binder, the coating exhibited good liquid repellency during water jetting and sandpaper abrasion tests. Furthermore, the coating has shown exceptional efficacy in terms of its ability to be anti-icing, anti-waxing, and self-cleaning.