In this paper we calculate some exact solutions of the grand partition functions for quantum gases in confined space, such as ideal gases in two- and three-dimensional boxes, in tubes, in annular containers, on the lateral surface of cylinders, and photon gases in three-dimensional boxes. Based on these exact solutions, which, of course, contain the complete information about the system, we discuss the geometry effect which is neglected in the calculation with the thermodynamic limit and analyze the validity of the quantum statistical method which can be used to calculate the geometry effect on ideal quantum gases confined in two-dimensional irregular containers. We also calculate the grand partition function for phonon gases in confined space. Finally, we discuss the geometry effects in realistic systems.
In this paper, we show that there exists an essential difference of boundary effects between Bose and Fermi systems both for Dirichlet and Neumann boundary conditions: at low temperatures and high densities the influence of the boundary on the Bose system depends on the temperature but is independent of the density, but for the Fermi case the influence of the boundary is independent of the temperature but depends on the density, after omitting the negligible high-order corrections. We also show that at high temperatures and low densities the difference of the influence of the boundary between Bose and Fermi systems appears in the next-to-leading order boundary contribution, and the leading boundary contribution is independent of the density. Moreover, for calculating the boundary effects at high temperatures and low densities, since the existence of the boundary modification causes the standard virial expansion to be invalid, we introduce a modified virial expansion.
In conventional scattering theory, to obtain an explicit result, one imposes a precondition that the distance between target and observer is infinite. With the help of this precondition, one can asymptotically replace the Hankel function and the Bessel function with the sine functions so that one can achieve an explicit result. Nevertheless, after such a treatment, the information of the distance between target and observer is inevitably lost. In this paper, we show that such a precondition is not necessary: without losing any information of distance, one can still obtain an explicit result of a scattering rigorously. In other words, we give an rigorous explicit scattering result which contains the information of distance between target and observer. We show that at a finite distance, a modification factor — the Bessel polynomial — appears in the scattering amplitude, and, consequently, the cross section depends on the distance, the outgoing wave-front surface is no longer a sphere, and, besides the phase shift, there is an additional phase (the argument of the Bessel polynomial) appears in the scattering wave function.