Compared to cross-linked polyethylene, polypropylene has a thermoplastic property and the advantage of recycling. However, the poor impact resistance at low temperature and the corresponding space charge problem restrict the application of polypropylene with the extruded high voltage direct current (HVDC) cable. Sufficient introduction of the β form of the polypropylene crystal can significantly improve impact resistance at low temperatures. Although it has been widely applied in insulation engineering, the effect of β-crystal on the space charge characteristics of polypropylene has rarely been researched until now. In this paper, a rare earth nucleating agent of β-crystal is employed to modify the performance of polypropylene to investigate the effects of nucleating agent content on β-crystalline, mechanical relaxation, trap, and space charge characteristics of polypropylene. The results of differential scanning calorimeter (DSC) and X-ray diffraction (XRD) tests indicate that the relative content of β-crystal in modified polypropylene increases gradually with the increasing concentration of the nucleating agent, approaching 43.5% when the nucleating agent content has been raised to 0.2 wt %, suggesting appreciable efficiency of the nucleating agent utilized in our research. Scanning electron microscopy (SEM) is utilized to characterize the morphology of β-crystal spherulites, which illustrates that the β-spherulites are in bunchy shape, and the lamellar crystals are parallel to each other without an obvious boundary between them. The results of the space charge test demonstrate that the modified polypropylene can substantially suppress space charge accumulation, which is attributed to an increment of β-crystal content by adopting a rare earth nucleating agent. It is indicated from dynamic mechanical analysis (DMA) measurements that the enhancement of β-crystalline in modified polypropylene can distinctly increase and decrease the β and α relaxation losses, respectively, which proves that the defects in β-crystal and amorphous regions are reduced and increased respectively. Thermally stimulated depolarization current tests further confirm that the number of traps caused by defects in the β-form of polypropylene crystal declines definitely, which dominantly accounts for the suppression of space charge accumulation.

Compared with traditional insulation materials, such as cross-linked polyethylene (XLPE), polypropylene (PP) is famous for its better recyclable and thermal properties, as well as its good electrical performance. However, the problem of poor impact strength has restricted the application of pure PP in high-voltage, direct current (HVDC) cables. In this paper, styrene-ethylene-butylene-styrene block copolymer (SEBS) was used as a toughening filler, and nano-SiO₂ was expected to improve the electric properties of the nano-composite. By controlling the masterbatch system, the dispersion characteristics of nano-SiO₂ in the ternary composite system were changed. When PP/SiO₂ was used as the masterbatch and then blended with SEBS, nano-SiO₂ tended to disperse in the PP phase, and the number of nano-particles in the SEBS phase was lower. When PP/SEBS was used as the masterbatch, nano-SiO₂ was distributed in both the PP phase and the SEBS phase. When SEBS/SiO₂ was used as the masterbatch, nano-SiO₂ tended to be dispersed in the SEBS phase. The different dispersion characteristics of nano-SiO₂ changed the crystallization and mechanical properties of the ternary composite system and produced different electrical performance improvement effects. The results of our experiment revealed that the space charge suppression capability was positively correlated with the direct current (DC) breakdown strength improvement effect. Compared with the DC performance of 500 kV commercial XLPE materials, the self-made PP-based ternary composite system has better space charge suppression effects and higher DC breakdown strength. When nano-SiO₂ was more dispersed in the PP phase, the space charge improvement effect was best. When the nano-SiO₂ particles were more dispersed in the SEBS phase, the expected electrical property improvement was not obtained. Scanning electron microscopy showed that the nano-SiO₂ particles in the SEBS phase were more dispersed at the interface than in the SEBS matrix, indicating that the nano-particles were poorly dispersed, which may be a reason why the electrical properties of the composite system were not significantly improved.

In order to achieve both high toughness and favorable dielectric properties of polypropylene materials, a styrene–butadiene–styrene block copolymer (SEBS) was employed as a toughening filler, in addition to a copolymerized polypropylene grafted by maleic anhydride (cPP-g-MAH) as a compatibilization modifier, to develop a novel isotactic polypropylene (iPP) composite (cPP-g-MAH/iPP/SEBS composite) with significantly improved direct-current (DC) dielectric performance and tenacity. The underlying physical and chemical mechanisms of modifying electric insulation were studied utilizing micro-structure characterization methods in combination with multiple thermal–mechanic–electric tests. The SEBS phase islands are uniformly distributed in the PP matrix with evidently improved dispersion due to cPP-g-MAH compatibilization. Compared with iPP, the elastic modulus of cPP-g-MAH/iPP/SEBS composites can be reduced by 58% with doubled thermal elongation, which is still superior to that of cross-linked polyethylene (XLPE), implying that the composites are qualified in terms of mechanical properties for use as power cables. The space charge accumulation and electric conduction are considerably suppressed in comparison with pure iPP and the iPP/SEBS composite. In the interest of charge-trapping characteristics modified by chemically grafting MAH, the deep traps introduced into polypropylene by grafting MAH were measured with a thermal stimulation current experiment to be 1.2 and 1.6 eV of energy level in trapping depth, verified through the first-principles electronic structure calculations with an all-electron numerical orbital scheme. It was concluded that the acquired high density of deep traps can effectively restrict the carrier transport and suppress the injection of space charge, resulting in a remarkable improvement of DC dielectric properties for the MAH grafted composites. The present work demonstrates that the cPP-g-MAH/iPP/SEBS composites are eligible to be applied to polypropylene-based high-voltage DC cables due to their excellent DC insulation performance, together with the appropriate mechanical properties.

To achieve a preferable compatibility between liquid silicone rubber (LSR) and cable main insulation in a cable accessory, we developed SiC/LSR nanocomposites with a significantly higher conductivity nonlinearity than pure LSR, whilst representing a notable improvement in space charge characteristics. Space charge distributions in polarization/depolarization processes and surface potentials of SiC/LSR composites are analyzed to elucidate the percolation conductance and charge trapping mechanisms accounting for nonlinear conductivity and space charge suppression. It is verified that SiC/LSR composites with SiC content higher than 10 wt% represent an evident nonlinearity of electric conductivity as a function of the electric field strength. Space charge accumulations can be inhibited by filling SiC nanoparticles into LSR, as illustrated in both dielectric polarization and depolarization processes. Energy level and density of shallow traps increase significantly with SiC content, which accounts for expediting carrier hopping transport and surface charge decay. Finite-element multiphysics simulations demonstrate that nonlinear conductivity acquired by 20 wt% SiC/LSR nanocomposite could efficiently homogenize an electric field distributed in high-voltage direct current (HVDC) cable joints. Nonlinear conductivities and space charge characteristics of SiC/LSR composites discussed in this paper suggest a feasible modification strategy to improve insulation performances of direct current (DC) cable accessories.