Valerian Hirschberg

Dr. Valerian Hirschberg

orcid

Research Focus & Metrics

Academic Career Length

7Years (2020-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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19 May 2023 in Journal of Polymer Science
Verified
Journal Article
Open access
VHValerian Hirschberg
Valerian Hirschberg
DRDenis Rodrigue
Denis Rodrigue
Polyamides (PA) are a family of engineering thermoplastics used in a wide range of applications including automotive, building, construction, separation processes, textiles, and so forth. This is related to their good properties (mechanical and thermal) which can also be modified by additives, other polymers (blends and multilayers) and fillers (composites). But these complex systems (several components) make the final materials more difficult to recycle. In this review, basic statistics on the production rate of polyamides are presented and the different recycling methods are reported to compare their advantages and limitations with respect to economics and technical analyses. The discussion includes biological, chemical, mechanical, physical, and thermal treatments to reintroduce, as much as possible, the parts after their end‐of‐service. Finally, a general conclusion on the current state of PA recycling is presented with several openings for future developments to satisfy the concept of circular economy and general sustainability.

5 March 2024 in Polymer
Verified
Journal Article
Open access
JZJian Zhang
Jian Zhang
VHValerian Hirschberg
Valerian Hirschberg
AGAnika Goecke
Anika Goecke
MWManfred Wilhelm
Manfred Wilhelm
WYWei Yu
Wei Yu
Denis RodrigueDenis Rodrigue
Denis Rodrigue

26 December 2022 in Recycling
Verified
Journal Article
Open access
PDF file
JZJian Zhang
Jian Zhang
VHValerian Hirschberg
Valerian Hirschberg
Denis RodrigueDenis Rodrigue
Denis Rodrigue
The mechanical properties of virgin/recycled high-density polyethylene (HDPE) blends over the complete concentration range was thoroughly investigated in this work. In particular, a focus was made on the long-term properties via mechanical fatigue. Two different mixing methods, namely powder mixing (dry blending) and extrusion mixing (melt blending), were used to determine the effect of processing conditions on the tensile and fatigue behavior of the blends after compression molding. It was found that both tensile (modulus, ultimate strength) and fatigue performances were improved with increasing vHDPE content. Based on the obtained data, a correlation between the blends composition and mechanical properties is reported. Moreover, it was observed that increasing the vHDPE content led to slower crack propagation rate, probably due to less defects (contamination) in the blends. Finally, a negligible difference in mechanical properties (fatigue resistance) between both mixing approaches was observed, but samples produced via powder mixing showed less viscous dissipation (heat generation) as the vHDPE content increased, leading to lower surface temperature rise which can be an advantage for specific applications.

28 June 2022 in Macromolecules
Verified
Journal Article
Closed access
MRMarie-Christin Röpert
Marie-Christin Röpert
MSMax G. Schußmann
Max G. Schußmann
MEMasood K. Esfahani
Masood K. Esfahani
MWManfred Wilhelm
Manfred Wilhelm
VHValerian Hirschberg
Valerian Hirschberg

16 December 2021 in Journal of Applied Polymer Science
Verified
Journal Article
Open access
PDF file
TZThomas Zink
Thomas Zink
LKLoredana Kehrer
Loredana Kehrer
VHValerian Hirschberg
Valerian Hirschberg
MWManfred Wilhelm
Manfred Wilhelm
TBThomas Böhlke
Thomas Böhlke
The nonlinear mechanical behavior of viscoelastic materials is modeled based on the Schapery integral model containing internal variables. In this context, a new approach for the strain‐dependent material properties is introduced considering a one‐dimensional formulation with strain‐dependent nonlinear functions for an oscillatory load case. In addition to the viscoelastic storage and loss modulus, the higher order harmonic oscillations in the stress response are computed and compared to experimental data from Fourier transform rheology of Polyamide 6 (PA6). The comparison reveals a good agreement between the predictions of the nonlinear model and the experimental data for the higher harmonic intensity .

4 July 2023 in Polymer Reviews
Verified
Journal Article
Closed access
JZJian Zhang
Jian Zhang
VHValerian Hirschberg
Valerian Hirschberg
Denis RodrigueDenis Rodrigue
Denis Rodrigue