The intercalation of layered compounds opens up a vast space of new host–guest hybrids, providing new routes for tuning the properties of materials. Here, it is shown that uniform and continuous layers of copper can be intercalated within the van der Waals gap of bulk MoS2 resulting in a unique Cu–MoS2 hybrid. The new Cu–MoS2 hybrid, which remains semiconducting, possesses a unique plasmon resonance at an energy of ≈1eV, giving rise to enhanced optoelectronic activity. Compared with high‐performance MoS2 photodetectors, copper‐enhanced devices are superior in their spectral response, which extends into the infrared, and also in their total responsivity, which exceeds 104 A W−1. The Cu–MoS2 hybrids hold promise for supplanting current night‐vision technology with compact, advanced multicolor night vision.
1 January 2011 in International Journal of Refractory Metals and Hard Materials
In this study, samples of zircaloy-2 were irradiated with oxygen ion beam (O5+ ions with 116 MeV energy) to fluence varying from 1013 to 1015 ion/cm2. The irradiated samples were observed under a transmission electron microscope to identify the irradiation-induced defects and phase transformations. Microstructural investigations on these samples showed the presence of interstitial defects and ZrO2 precipitates in the α (hcp) matrix. The alignment of defects appeared to facilitate the formation of the ZrO2 phase in the irradiated samples. Orientation relationship between the oxide and the matrix phase was determined and a possible mechanism for the formation of the ZrO2 phase based on the entrapment of the oxygen ions has been proposed.