Maurizio Vignolo

Dr. Maurizio Vignolo

SCITEC Genova, National Research Council, Rome, Lazio, Italy
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Research Focus & Metrics

Academic Career Length

23Years (2004-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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1 June 2004 in Physical Chemistry Chemical Physics
Verified
Journal Article
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OCO. Cavalleri
O. Cavalleri
GGG. Gonella
G. Gonella
STS. Terreni
S. Terreni
Maurizio VignoloMaurizio Vignolo
Maurizio Vignolo
LFL. Floreano
L. Floreano
RRR. Rolandi
R. Rolandi
The increasing demand for heterogeneous materials prompts the interest for the physics and chemistry of organic–inorganic interfaces. Within this field of interest we have investigated the electronic states of L-cysteine (Cys) adsorbed on Au(111) from aqueous solution with synchrotron-based, high resolution X-ray photoemission spectroscopy. The analysis of the S 2p core level region in pristine samples prepared with purified Cys indicates that Cys adsorbs on gold as a thiolate. The absence of a signal related to physisorbed sulfur indicates that Cys forms a monomolecular layer. The high resolution allowed us to resolve two components in the C 1s spectral region related to carboxyl. The comparative analysis of C 1s, N 1s and O 1s core level regions indicates the presence of the neutral and ionic form for both the carboxyl and the amine groups. From the quantitative analysis of the C 1s and N 1s data we can infer that the zwitterionic form is the prevalent one, with a ratio of zwitterionic to neutral molecules of 3∶1. This value is quite different from that in the deposition solution. Prolonged exposure to the X-ray beam and thermal annealing induce the formation of atomic sulfur through S–C bond breaking and molecular fragment desorption. This response to X-ray irradiation differs from the results recently reported on long chain alkanethiols.

23 April 2010 in Superconductor Science and Technology
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Journal Article
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MTM Tropeano
M Tropeano
IPI Pallecchi
I Pallecchi
MCM R Cimberle
M R Cimberle
CFCarlo Ferdeghini
Carlo Ferdeghini
GLG Lamura
G Lamura
MPM Putti
M Putti

15 November 2008 in Journal of Applied Physics
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Journal Article
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AMA. Malagoli
A. Malagoli
VBV. Braccini
V. Braccini
MTM. Tropeano
M. Tropeano
Maurizio VignoloMaurizio Vignolo
Maurizio Vignolo
CBC. Bernini
C. Bernini
DLD. C. Larbalestier
D. C. Larbalestier
Ex situ powder-in-tube MgB2 tapes prepared with ball-milled, undoped powders showed a strong enhancement of the irreversibility field H∗ , the upper critical field Hc2 , and the critical current density Jc(H) together with the suppression of the anisotropy of all of these quantities. Jc reached 104 A/cm2 at 4.2 K and 10 T, with an irreversibility field of about 14 T at 4.2 K, and Hc2 of 9 T at 25 K, high values for not-doped MgB2 . The enhanced Jc and H∗ values are associated with significant grain refinement produced by milling of the MgB2 powder, which enhances grain boundary pinning, even if at the same time also reducing the connectivity from about 12% to 8%. Although enhanced pinning and diminished connectivity are in opposition, the overall influence of ball milling on Jc is positive because the increased density of grains with a size comparable with the mean free path produces strong electron scattering that substantially increases Hc2 , especially Hc2 perpendicular to the Mg and B planes.

29 June 2005 in Physical Review B
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IPI. Pallecchi
I. Pallecchi
CTC. Tarantini
C. Tarantini
HAH. U. Aebersold
H. U. Aebersold
VBV. Braccini
V. Braccini
CFC. Fanciulli
C. Fanciulli
MPM. Putti
M. Putti
We study the effect of neutron irradiation on the critical current density Jc of isotopically pure polycrystalline MgB211 samples. For fluences in the range 1017–1018cm−2, Jc is enhanced and its dependence on magnetic field is significantly improved: we demonstrate that, in this regime, pointlike pinning centers are effectively introduced in the system proportionally to the neutron fluence. Instead, for larger fluences, a strong suppression of the critical temperature accompanied by a decrease of both the upper critical field Bc2 and Jc is found.

18 October 2011 in Physical Review B
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IPIlaria Pallecchi
Ilaria Pallecchi
FBF. Bernardini
F. Bernardini
MTM. Tropeano
M. Tropeano
APA. Palenzona
A. Palenzona
AMAlberto Martinelli
Alberto Martinelli
MPM. Putti
M. Putti
In this paper, we investigate the Ru-substituted LaFeAsO compound by studying the magnetotransport behavior and its relationship with the band structure in different regimes of temperature, magnetic field, and Ru content. In particular, we analyze the magnetoresistance of LaFe1$-${}xRuxAsO (0 $\le${} x $\le${} 0.6) samples with the support of ab initio calculations, and we find that in the whole series: (i) the transport is dominated by electron bands only; (ii) the magnetoresistance exhibits distinctive features related to the presence of Dirac cones; indeed, ab initio calculations confirm the presence of anisotropic Dirac cones in the band structure; (iii) the low temperature mobility is exceptionally high and reaches 18.6 m2/(Vs) in the Ru-free sample at T\,=\,2 K in the extreme limit of a single Landau level occupied in the Dirac cones; (iv) the mobility drops abruptly above 10\char21{}15 K; (v) the disorder has a very weak effect on the band mobilities and on the transport properties; and (vi) there exists a correlation between the temperature ranges of Dirac cones and SDW carrier condensation. These findings evidence the outstanding transport properties of Dirac cones in Fe-based pnictides parent compounds.

30 January 2019 in IEEE Transactions on Applied Superconductivity
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Journal Article
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ABAmalia Ballarino
Amalia Ballarino
SHSimon Hopkins
Simon Hopkins
BBBernardo Bordini
Bernardo Bordini
DRDavid Richter
David Richter
DTDavide Tommasini
Davide Tommasini
CFCarlo Ferdeghini
Carlo Ferdeghini
The study of next generation high energy accelerators based on 16 T dipoles has emphasized the need for higher performance, cost-effective $Nb_{3}Sn$ superconducting wires. A Conductor Development Program aiming to reach a non-copper critical current density ( $J_{c}$ ) of 1500 $A/mm^2$ at 16 T and 4.2 K has been launched by CERN, with the involvement of industry and laboratories worldwide. In this article, the targets and strategy of the program are presented, with an overview of the wire layouts and development activities being pursued by each partner, and the latest characterization results are reported. Three of the four participating manufacturers have successfully reached the first stage $J_{c}$ milestone, but a significant advance is still needed to achieve the final target. The next steps are briefly discussed, as the program focuses increasingly on novel alloys and methods to maximize $J_{c}$ .