Incorporating foliar zinc (Zn) spray into existing pesticide application is considered highly cost-effective to biofortify wheat (Triticum aestivum) with Zn. However, the effectiveness of this combined approach in terms of Zn enrichment and bioavailability in grain and its milling fractions is not well examined. Two-year field experiments were conducted in 2017 and 2018 with three sets of foliar applications (nil Zn as control, foliar Zn alone, and foliar Zn plus pesticides) at the anthesis, milk stage, or both. Compared to the control, grain yield was not affected by foliar Zn application alone or combined with pesticides, while the Zn concentrations and bioavailability substantially increased in the whole-grain, bran, and flour irrespective of spray timing. Yield losses by 28%–39% (2018 vs. 2017) led to 7%–18% and 18%–38% increase of Zn density in grain and flour, respectively. Further, such negative responses were uncoupled by foliar spray of Zn or Zn plus pesticides, and absent from the control plants. Nonetheless, grain Zn biofortification was achieved in both low- and high-yield plants with either Zn spray alone or combined with pesticides. Together with the enhanced Zn bioavailability in grain, bran, and flour, the effectiveness of this combined strategy is validated to biofortify wheat with Zn.

Worldwide solar dimming from the 1960s to the 1980s has been widely recognized, but the occurrence of solar brightening since the late 1980s is still under debate—particularly in China. This study aims to properly examine the biases of urbanization in the observed sunshine duration series from 1987 to 2016 and explore the related driving factors based on five meteorological stations around Hangzhou City, China. The results inferred a weak and insignificant decreasing trend in annual mean sunshine duration (−0.09 h/d decade⁻¹) from 1987 to 2016 in the Hangzhou region, indicating a solar dimming tendency. However, large differences in sunshine duration changes between rural, suburban, and urban stations were observed on the annual, seasonal, and monthly scales, which can be attributed to the varied urbanization effects. Using rural stations as a baseline, we found evident urbanization effects on the annual mean sunshine duration series at urban and suburban stations—particularly in the period of 2002–2016. The effects of urbanization on the annual mean sunshine duration trends during 1987−2016 were estimated to be −0.16 and −0.35 h/d decade⁻¹ at suburban and urban stations, respectively. For urban stations, the strongest urbanization effect was observed in summer (−0.46 h/d decade⁻¹) on the seasonal scale and in June (−0.63 h/d decade⁻¹) on the monthly scale. The notable negative impact of urbanization on local solar radiation changes was closely related to the changes in anthropogenic pollutions, which largely reduced the estimations of solar radiation trends in the Hangzhou region. This result highlights the necessity to carefully consider urbanization impacts when analyzing the trend in regional solar radiation and designing cities for sustainable development.