Ferrous Metallurgy Department, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No.30 Xueyuan Road, Haidian District, Beijing 100083, China
Dr. Haiyan Tang
Ferrous Metallurgy Department, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No.30 Xueyuan Road, Haidian District, Beijing 100083, China
The tundish with heating instrumentation is attracting more and more attention in continuous casting processes for maintaining a pre-determined constant pouring temperature under a given casting speed, which is beneficial for an improved and consistent steel product quality. However, the fluid flow, temperature distribution and the removal behaviors of non-metallic inclusions in it will be much different from that in a conventional tundish, due to the implementation of the heating practice. In the present work, to reduce the non-metallic inclusion amounts in billets of the second and sixth strands in a seven-strand tundish with channel type induction heating, the flow field profiles and temperature profiles of molten steel in this tundish have been investigated using hydrodynamic modeling coupled with mathematical simulation under isothermal and non-isothermal situations, respectively. The results of the isothermal experiment indicate that the prototype tundish has severe “short-circuiting flow” in the second and sixth strands, which might have caused the increased inclusion amounts in the billets of the two strands. The flow field of the tundish can be greatly improved by changing the channel design and adding two high dams at each side of the tundish. Compared with the prototype structure A0, the average residence time of the optimized case C5 is prolonged by 55.49% (from 501 to 779 s); the dead zone volume fraction is reduced by 66.18% (from 45.57% to 15.41%); and the flow of each strand becomes more consistent with lower standard deviation. The non-isothermal experiments show that the fluid presents an obvious rising tendency when it flows out from the heating induction channel. The larger the temperature difference inside and outside the channel is, the more consistent the fluid flow between different strands and the more homogeneous the flow field in the whole tundish. For the prototype tundish structure, when the temperature difference is 5 °C, the dead zone is basically eliminated, and the minimum residence time is prolonged by 789% (from 38 to 338 s), compared with the 0 °C of temperature difference. A mathematic model has been proposed accordingly, which can explain well the hydraulic phenomena. The inclusion removal rates of different cases were compared by mathematical simulation, and their removal mechanism was studied, as well.
10 February 2019 in Ironmaking & Steelmaking: Processes, Products and Applications
A novel gas blowing mode with different flowrates for two plugs of metallurgical ladle is explored and studied through a sophisticated water model. The results show that this mode can efficiently decrease the mixing time and the total area of the slag eye for most cases, as compared with the conventional mode with same flowrates for two plugs. Generally, a relatively close angle between the porous plugs and a small radial position are beneficial to a decrease in the mixing time of bath, while a relatively far plug radial position leads to a smaller slag eye. In addition, tracers fed from the middle of the dual plugs are proven to be very beneficial to the mixing of the ladle. The slag layer will prolong the mixing time due to its consumption on the stirring energy compared with the situation without slag.
Steel casing pipes used in the construction of deep oil wells usually require both high strength and corrosion-resistant behavior. Due to the exploration of deep H2S-bearing oil reservoirs, sulfide stress cracking (SSC) is becoming an increasingly serious concern for casing steel. The nonmetallic inclusions in the steel are among the key reasons for its service failure. The rare earth element Ce can be used to modify the inclusions in casing steel and improve its SSC resistance. Here, taking C110 grade casing steel (the highest class currently in service) as the investigated object, the modification behavior of Ce inclusions in the steel and the effect of the addition of Ce in varying amounts (0.01, 0.024, and 0.042 wt.%) on the modified products were studied through high-temperature tube furnace experiments and thermodynamic calculations. The results showed that Ce had an obvious modification effect on the CaO·Al2O3 inclusions in casing steel, and the diffusion of dissolved Ce in the steel was the limiting step of the modification reaction. With the extension of reaction time, the sequence describing the modification of inclusions in the steel was determined as follows: CaO·Al2O3 → CeAlO3 → Ce2O3/Ce2O2S. The final stable product after modification depended on the amount of Ce added. With 0.01 wt.% Ce, the stable phase in molten steel was Ce2O3; on the other hand, upon adding ≥0.024 wt.% Ce, the stable phase became Ce2O2S. In addition, the thermodynamic stability of Ce2O3 decreased, and it was transformed into CeAlO3, Ce2O2S, Ce2S3, and CeS during solidification. On the basis of our results and the considerations for smooth casting, the addition of a proper amount of a rare earth element is suggested for industrial trials, following the achievement of a significant and surprising improvement in the qualified rate of SSC resistance for the final steel products. The relevant mechanism is also analyzed.
6 March 2022 in Metallurgical and Materials Transactions B