An analysis of chemical composition data of particulate matter samples (TSP, PM₁₀ and PM_2.5) collected from 2002 to 2008 in the North Atlantic free troposphere at the Izaña Global Atmospheric Watch (GAW) observatory (Tenerife, Canary Islands) shows that desert dust is very frequently mixed with particulate pollutants in the Saharan Air Layer (SAL). The study of this data set with Median Concentrations At Receptor (MCAR) plots allowed the identification of the potential source regions of the dust and particulate pollutants. Areas located at the south of the southern slope of the Atlas mountains emerge as the most frequent source of the soil desert dust advected to the northern edge of the SAL in summer. Industrial emissions occurring in Northern Algeria, Eastern Algeria, Tunisia and the Atlantic coast of Morocco appear as the most important source of the nitrate, ammonium and a fraction of sulphate (at least 60 % of the sulphate <10 μm transported from some regions) observed in the SAL. These emissions are mostly linked to crude oil refineries, phosphate-based fertilizer industry and power plants. Although desert dust emissions appear as the most frequent source of the phosphorous observed in the SAL, high P concentrations are observed when the SAL is affected by emissions from open mines of phosphate and phosphate based fertilizer industry. The results also show that a significant fraction of the sulphate (up to 90 % of sulphate <10 μm transported from some regions) observed in the SAL may be influenced by soil emissions of evaporite minerals in well defined regions where dry saline lakes (chotts) are present. These interpretations of the MCAR plots are consistent with the results obtained with the Positive Matrix Factorization (PMF2) receptor modelling. The results of this study show that North African industrial pollutants may be mixed with desert dust and exported to the North Atlantic in the Saharan Air Layer.

The occurrence of African dust outbreaks over different areas of the western Mediterranean Basin were identified on an 11-year period (2001–2011). The main atmospheric circulation patterns causing the transport of African air masses were characterized by means of an objective classification methodology of atmospheric variable fields. Next, the potential source areas of mineral dust, associated to each circulation pattern were identified by trajectory statistical methods. Finally, an impact index was calculated to estimate the incidence of the African dust outbreaks produced during each circulation pattern, in the areas of study. Four circulation types were obtained (I–IV) and three main potential source areas of African dust were identified (Western Sahara and Morocco; Algeria; northeastern Algeria and Tunisia). The circulation pattern I (24% of the total number of episodic days) produced the transport of dust mainly in summer from Western Sahara, southern Morocco and Tunisia. The circulation pattern IV (33%) brings dust mainly from areas of northern and southern Algeria in summer and autumn, respectively. The circulation pattern II (31%) favored the transport of dust predominantly from northern Algeria, both in spring and summer. Finally, the circulation type III was the less frequently observed (12%). It occurred mainly in spring and with less intensity in winter, carrying dust from Western Sahara and southern Morocco. Our findings point out that the most intense episodes over the western Mediterranean Basin were produced in the summer period by the circulation type I (over the western side of the Iberian Peninsula) and the circulation type IV (over the central and eastern sides of the Iberian Peninsula and the Balearic Islands).

We have studied the relationship between the long-term interannual variability in large-scale meteorology in western North Africa – the largest and most active dust source worldwide – and Saharan dust export in summer, when enhanced dust mobilization in the hyper-arid Sahara results in maximum dust impacts throughout the North Atlantic. We address this issue by analyzing 28 years (1987–2014) of summer averaged dust concentrations at the high-altitude Izaña observatory (~ 2400 m a.s.l.) on Tenerife, and satellite and meteorological reanalysis data. The summer meteorological scenario in North Africa (aloft 850 hPa) is characterized by a high over the the subtropical Sahara and a low over the tropics linked to the monsoon. We measured the variability of this high–low dipole-like pattern in terms of the North African dipole intensity (NAFDI): the difference of geopotential height anomalies averaged over the subtropics (30–32° N, Morocco) and the tropics (10–13° N, Bamako region) close to the Atlantic coast (at 5–8° W). We focused on the 700 hPa standard level due to dust export off the coast of North Africa tending to occur between 1 and 5 km a.s.l. Variability in the NAFDI is associated with displacements of the North African anticyclone over the Sahara and this has implications for wind and dust export. The correlations we found between the 1987–2014 summer mean of NAFDI with dust at Izaña, satellite dust observations and meteorological re-analysis data indicate that increases in the NAFDI (i) result in higher wind speeds at the north of the Inter-Tropical Convergence Zone that are associated with enhanced dust export over the subtropical North Atlantic, (ii) influence the long-term variability of the size distribution of exported dust particles (increasing the load of coarse dust) and (iii) are associated with enhanced rains in the tropical and northern shifts of the tropical rain band that may affect the southern Sahel. Interannual variability in NAFDI is also connected to spatial distribution of dust over the North Atlantic; high NAFDI summers are associated with major dust export (linked to winds) in the subtropics and minor dust loads in the tropics (linked to higher rainfall), and vice versa. The evolution of the summer NAFDI values since 1950 to the present day shows connections to climatic variability (through the Sahelian drought, ENSO (El Niño–Southern Oscillation) and winds) that have implications for dust export paths. Efforts to anticipate how dust export may evolve in future decades will require a better understanding of how the large-scale meteorological systems represented by the NAFD will evolve.

An analysis of the 22-yr ozone (O₃) series (1988–2009) at the subtropical high mountain Izaña~station (IZO; 2373 m a.s.l.), representative of free troposphere (FT) conditions, is presented. Diurnal and seasonal O₃ variations as well as the O₃ trend (0.19 ± 0.05 % yr⁻¹ or 0.09 ppbv yr⁻¹), are assessed. A climatology of O₃ transport pathways using backward trajectories shows that higher O₃ values are associated with air masses travelling above 4 km altitude from North America and North Atlantic Ocean, while low O₃ is transported from the Saharan continental boundary layer (CBL). O₃ data have been compared with PM₁₀, ²¹⁰Pb, ⁷Be, potential vorticity (PV) and carbon monoxide (CO). A clear negative logarithmic relationship was observed between PM₁₀ and surface O₃ for all seasons. A similar relationship was found between O₃ and ²¹⁰Pb. The highest daily O₃ values (90th percentile) are observed in spring and in the first half of summer time. A positive correlation between O₃ and PV, and between O₃ and ⁷Be is found throughout the year, indicating that relatively high surface O₃ values at IZO originate from the middle and upper troposphere. We find a good correlation between O₃ and CO in winter, supporting the hypothesis of long-range transport of photochemically generated O₃ from North America. Aged air masses, in combination with sporadic inputs from the upper troposphere, are observed in spring, summer and autumn. In summer time high O₃ values seem to be the result of stratosphere-to-troposphere (STT) exchange processes in regions neighbouring the Canary Islands. Since 1995–1996, the North Atlantic Oscillation has changed from a predominantly high positive phase to alternating between negative, neutral or positive phases. This change results in an increased flow of the westerlies in the mid-latitude and subtropical North Atlantic, thus favouring the transport of O₃ and its precursors from North America, and a higher frequency of storms over North Atlantic, with a likely higher incidence of STT processes in mid-latitudes. These processes lead to an increase of tropospheric O₃ in the subtropical North Atlantic region after 1996 that has been reflected in surface O₃ records at IZO.

More than 2 years of columnar atmospheric aerosol measurements (2006–2009) at the Tamanrasset site (22.79° N, 5.53° E, 1377 m a.s.l.), in the heart of the Sahara, are analysed. Aerosol Robotic Network (AERONET) level 2.0 data were used. The KCICLO (K is the name of a constant and ciclo means cycle in Spanish) method was applied to a part of the level 1.5 data series to improve the quality of the results. The annual variability of aerosol optical depth (AOD) and Ångström exponent (AE) has been found to be strongly linked to the convective boundary layer (CBL) thermodynamic features. The dry-cool season (autumn and winter) is characterized by a shallow CBL and very low mean turbidity (AOD ~ 0.09 at 440 nm, AE ~ 0.62). The wet-hot season (spring and summer) is dominated by high turbidity of coarse dust particles (AE ~ 0.28, AOD ~ 0.39 at 440 nm) and a deep CBL. The aerosol-type characterization shows desert mineral dust as the prevailing aerosol. Both pure Saharan dust and very clear sky conditions are observed depending on the season. However, several case studies indicate an anthropogenic fine mode contribution from the industrial areas in Libya and Algeria. The concentration weighted trajectory (CWT) source apportionment method was used to identify potential sources of air masses arriving at Tamanrasset at several heights for each season. Microphysical and optical properties and precipitable water vapour were also investigated.