We observed ozone (O₃) in the vertical region between 250 and 0.0005 hPa (~ 12–96 km) using the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) on the Japanese Experiment Module (JEM) of the International Space Station (ISS) between 12 October 2009 and 21 April 2010. The new 4 K superconducting heterodyne receiver technology of SMILES allowed us to obtain a one order of magnitude better signal-to-noise ratio for the O₃ line observation compared to past spaceborne microwave instruments. The non-sun-synchronous orbit of the ISS allowed us to observe O₃ at various local times. We assessed the quality of the vertical profiles of O₃ in the 100–0.001 hPa (~ 16–90 km) region for the SMILES NICT Level 2 product version 2.1.5. The evaluation is based on four components: error analysis; internal comparisons of observations targeting three different instrumental setups for the same O₃ 625.371 GHz transition; internal comparisons of two different retrieval algorithms; and external comparisons for various local times with ozonesonde, satellite and balloon observations (ENVISAT/MIPAS, SCISAT/ACE-FTS, Odin/OSIRIS, Odin/SMR, Aura/MLS, TELIS). SMILES O₃ data have an estimated absolute accuracy of better than 0.3 ppmv (3%) with a vertical resolution of 3–4 km over the 60 to 8 hPa range. The random error for a single measurement is better than the estimated systematic error, being less than 1, 2, and 7%, in the 40–1, 80–0.1, and 100–0.004 hPa pressure regions, respectively. SMILES O₃ abundance was 10–20% lower than all other satellite measurements at 8–0.1 hPa due to an error arising from uncertainties of the tangent point information and the gain calibration for the intensity of the spectrum. SMILES O₃ from observation frequency Band-B had better accuracy than that from Band-A. A two month period is required to accumulate measurements covering 24 h in local time of O₃ profile. However such a dataset can also contain variation due to dynamical, seasonal, and latitudinal effects.

Understanding the atmospheric distribution of water (H ${}_2$ O) is crucial for global warming studies and climate change mitigation. In this context, reliable satellite data are extremely valuable for their global and continuous coverage, once their quality has been assessed. Short-wavelength infrared spectra are acquired by the Thermal And Near-infrared Sensor for carbon Observation-Fourier Transform Spectrometer (TANSO-FTS) aboard the Greenhouse gases Observing Satellite (GOSAT). From these, column-averaged dry-air mole fractions of carbon dioxide, methane and water vapor (XH ${}_2$ O) have been retrieved at the National Institute for Environmental Studies (NIES, Japan) and are available as a Level 2 research product. We compare the NIES XH ${}_2$ O data, Version 02.21, with retrievals from the ground-based Total Carbon Column Observing Network (TCCON, Version GGG2014). The datasets are in good overall agreement, with GOSAT data showing a slight global low bias of −3.1% $\pm$ 24.0%, good consistency over different locations (station bias of −1.53% $\pm$ 10.35%) and reasonable correlation with TCCON (R = 0.89). We identified two potential sources of discrepancy between the NIES and TCCON retrievals over land. While the TCCON XH ${}_2$ O amounts can reach 6000–7000 ppm when the atmospheric water content is high, the correlated NIES values do not exceed 5500 ppm. This could be due to a dry bias of TANSO-FTS in situations of high humidity and aerosol content. We also determined that the GOSAT-TCCON differences directly depend on the altitude difference between the TANSO-FTS footprint and the TCCON site. Further analysis will account for these biases, but the NIES V02.21 XH ${}_2$ O product, after public release, can already be useful for water cycle studies.

We retrieved lower stratospheric vertical profiles of O₃, HNO₃, and HCl from solar spectra taken with a ground-based Fourier transform infrared spectrometer (FTIR) installed at Syowa Station, Antarctica (69.0^∘ S, 39.6^∘ E), from March to December 2007 and September to November 2011. This was the first continuous measurement of chlorine species throughout the ozone hole period from the ground in Antarctica. We analyzed temporal variation of these species combined with ClO, HCl, and HNO₃ data taken with the Aura MLS (Microwave Limb Sounder) satellite sensor and ClONO₂ data taken with the Envisat MIPAS (the Michelson Interferometer for Passive Atmospheric Sounding) satellite sensor at 18 and 22 km over Syowa Station. An HCl and ClONO₂ decrease occurred from the end of May at both 18 and 22 km, and eventually, in early winter, both HCl and ClONO₂ were almost depleted. When the sun returned to Antarctica in spring, enhancement of ClO and gradual O₃ destruction were observed. During the ClO-enhanced period, a negative correlation between ClO and ClONO₂ was observed in the time series of the data at Syowa Station. This negative correlation was associated with the relative distance between Syowa Station and the edge of the polar vortex. We used MIROC3.2 chemistry–climate model (CCM) results to investigate the behavior of whole chlorine and related species inside the polar vortex and the boundary region in more detail. From CCM model results, the rapid conversion of chlorine reservoir species (HCl and ClONO₂) into Cl₂, gradual conversion of Cl₂ into Cl₂O₂, increase in HOCl in the winter period, increase in ClO when sunlight became available, and conversion of ClO into HCl were successfully reproduced. The HCl decrease in the winter polar vortex core continued to occur due to both transport of ClONO₂ from the subpolar region to higher latitudes, providing a flux of ClONO₂ from more sunlit latitudes into the polar vortex, and the heterogeneous reaction of HCl with HOCl. The temporal variation of chlorine species over Syowa Station was affected by both heterogeneous chemistries related to polar stratospheric cloud (PSC) occurrence inside the polar vortex and transport of a NO_x-rich air mass from the polar vortex boundary region, which can produce additional ClONO₂ by reaction of ClO with NO₂. The deactivation pathways from active chlorine into reservoir species (HCl and/or ClONO₂) were confirmed to be highly dependent on the availability of ambient O₃. At 18 km, where most ozone was depleted, most ClO was converted to HCl. At 22 km where some O₃ was available, an additional increase in ClONO₂ from the prewinter value occurred, similar to the Arctic.

Submillimeter-Wave Limb-Emission Sounder 2 (SMILES-2) is a satellite mission proposed in Japan to probe the middle and upper atmosphere (20–160 km). The main instrument is composed of 4 K cooled radiometers operating near 0.7 and 2 THz. It could measure the diurnal changes of the horizontal wind above 30 km, temperature above 20 km, ground-state atomic oxygen above 90 km and atmospheric density near the mesopause, as well as abundance of about 15 chemical species. In this study we have conducted simulations to assess the wind, temperature and density retrieval performance in the mesosphere and lower thermosphere (60–110 km) using the radiometer at 760 GHz. It contains lines of water vapor (H₂O), molecular oxygen (O₂) and nitric oxide (NO) that are the strongest signals measured with SMILES-2 at these altitudes. The Zeeman effect on the O₂ line due to the geomagnetic field (B) is considered; otherwise, the retrieval errors would be underestimated by a factor of 2 above 90 km. The optimal configuration for the radiometer’s polarization is found to be vertical linear. Considering a retrieval vertical resolution of 2.5 km, the line-of-sight wind is retrieved with a precision of 2–5 m s⁻¹ up to 90 km and 30 m s⁻¹ at 110 km. Temperature and atmospheric density are retrieved with a precision better than 5 K and 7 % up to 90 km (30 K and 20 % at 110 km). Errors induced by uncertainties on the vector B are mitigated by retrieving it. The retrieval of B is described as a side-product of the mission. At high latitudes, precisions of 30–100 nT on the vertical component and 100–300 nT on the horizontal one could be obtained at 85 and 105 km (vertical resolution of 20 km). SMILES-2 could therefore provide the first measurements of B close to the electrojets' altitude, and the precision is enough to measure variations induced by solar storms in the auroral regions.

We observed the diurnal variation of ozone (O3) in the vertical region between 250 and 0.0005 hPa (~12–96 km) using the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) on the Japanese Experiment Module (JEM) of the International Space Station (ISS) between 12 October 2009 and 21 April 2010. The new 4 K superconducting heterodyne receiver technology of SMILES allowed us to obtain a one order of magnitude better signal-to-noise ratio for the O3 line observation compared to past spaceborne microwave instruments. We assessed the quality of the vertical profiles of O3 in the 100–0.001 hP (~16–90 km) region for the SMILES NICT Level 2 product version 2.1.5. The evaluation is based on four components; error analysis; internal comparisons of observations targeting three different instrumental setups for the same O3 625.371 GHz transition; internal comparisons of two different retrieval algorithms; and external comparisons for various local times with ozonesonde, satellite and balloon observations (ENVISAT/MIPAS, SCISAT/ACE-FTS, Odin/OSIRIS, Odin/SMR, Aura/MLS, TELIS). SMILES O3 data have an estimated absolute accuracy of better than 0.3 ppmv (3%) with a vertical resolution of 3–4 km over the 60 to 8 hPa range. The random error for a single measurement is better than the estimated systematic error, being less than 1, 2, and 7%, in the 40–1, 80–0.1, and 100–0.004 hPa pressure region, respectively. SMILES O3 abundance was 10–20% lower than all other satellite measurements at 8–0.1 hPa due to an error arising from uncertainties of the tangent point information and the calibration problem for the intensity of the spectrum. The non sun-synchronous orbit of the ISS allowed us to observe O3 at various local times. A two month period is required to accumulate measurements covering 24 h in local time. However such a dataset can also contain variation due to dynamical, seasonal, and latitudinal effects.

Submillimeter-Wave Limb-Emission Sounder-2 (SMILES-2) is a satellite mission proposed in Japan to probe the middle and upper-atmosphere (20–160 km). The main instrument is composed of 4-K cooled radiometers operating near 0.7 and 2 THz. It could measure the diurnal changes of the horizontal wind above 30 km, temperature above 20 km, ground-state atomic oxygen above 90 km, atmospheric density near the mesopause, as well as abundance of about 15 chemical species. In this study we have conducted simulations to assess the wind, temperature and density retrieval performance in the mesosphere and lower thermosphere (60–110 km) using the radiometer at 760 GHz. It contains lines of water vapor (H2O), molecular oxygen (O2) and nitric oxide (NO) that are the strongest signals measured with SMILES-2 at these altitudes. The Zeeman effect on the O2 line due to the geomagnetic field (B) is considered, otherwise, the retrieval errors would be underestimated by a factor of 2 above 90 km. The optimal configuration for the radiometer’s polarization is found to be vertical linear. The line-of-sight wind is retrieved with a precision of 2–5 m/s up to 90 km (30 m/s at 110 km) and a vertical resolution of 2.5 km. Temperature and atmospheric density are retrieved with a precision better than 5 K (30 K) and 7 % (20 %) up to 90 km (110 km), respectively. Errors induced by uncertainties on the vector B are mitigated by retrieving it. The retrieval of B is described as a side-product of the mission. At high-latitudes, precisions of 30–100 nT on the vertical component and 100–300 nT on the horizontal one could be obtained at 85 and 105 km (vertical resolution of 20 km). SMILES-2 could therefore provide the first measurements of B close to the electrojets' altitude, and the precision is enough to measure variations induced by solar storms in the auroral regions.