Polymer nanocomposites are increasingly used in applications that are subjected to harsh environments. Owing to polymer's susceptibility to photodegradation, nanofillers in a polymer nanocomposite may be released into the environments during the composite's life cycle. Such release potentially poses an environmental health and safety problem and may hinder commercialization of these advanced materials. This study investigated the fate and release of nanosilica from epoxy/nanosilica composites. Specially-designed holders containing nanocomposite specimens were irradiated with UV light in a well-controlled environmental chamber. UV irradiated samples were removed for measurements of polymer chemical degradation, mass loss, surface morphology, nanosilica accumulation on the composite surface, and nanosilica release. Epoxy matrix underwent rapid photodegradation, resulting in substantial accumulation of silica nanofillers on the composite surface and also release from the composite. A conceptual model for surface accumulation and release of nanosilica during UV irradiation of epoxy nanocomposites is presented.
6 July 2011 in Journal of Physics: Conference Series
In water treatment by microfiltration and ultrafiltration, a major concern is the integrity loss or failure of membrane induced by onsite operations, potentially leading to permeate water contamination. This study aims to provide a better understanding of the phenomena responsible for membrane damage by analyzing its causes and effects. The role of sodium hypochlorite exposure conditions and the impact of mechanical stress on membrane characteristics were investigated. Monitoring of hydraulic response, mechanical properties and the evolution of the chemical structure showed, on multiple scales, strong indications of membrane chemical degradation, involving radical mechanisms, accelerated by tensile stress application.
On most modern airliners, cabin air pressurization, heating, and renewal are mainly achieved using air supplied from the gas turbine engines during flight. This air intake impairs the motors yield and needs to be conditioned, leading to energy overconsumption. Recent advances in thermal management enable aircraft manufacturers to reduce further the intake airflow needed to maintain cabin temperature at high altitude. Nevertheless, for lower air renewal rates, an appropriate air filtration system will be needed to maintain acceptable air quality in the cabin. In this context, Clean Sky 2 Joint Undertaking (CS2JU) project EC2S (Environment Control Secondary System) aims at developing an integrated filtration system to be implemented in existing cabin air management systems (so-called environmental control system—ECS). The EC2S unit will include three filtration units addressing separately volatile organic compounds (VOCs), CO2, and particulate matter (PM). Circulated air in the ECS is conventionally filtered on pleated HEPA filters that generate substantial pressure drop. Since the EC2S VOCs and CO2 filtration units would generate additional pressure drop in the ECS system, electrostatic precipitation is foreseen as a low flow resistance alternative for PM removal. This paper reports the development and performance assessment of a two-stage electrostatic precipitator (ESP) designed for aircraft recirculated air filtration. The ESP prototype presents high single-pass particle collection rates (i.e., over 90% for airborne particles with an aerodynamic diameter of 0.5 μm or larger), low-pressure drop (i.e., 4 Pa at nominal flowrate), and a limited ozone generation rate (i.e., below 8 mg h−1).