Tantalum is an important metal for high-technology applications of the modern world. It is recovered from oxide minerals that are present as minor constituents in rare-metal granites (RMG) and granitic rare-element pegmatites (REP). Significant potential exists as a by-product of spodumene mining from pegmatites, and from Nb-Zr-rare earth element (REE) mining from carbonatites and peralkaline igneous rocks. Columbite-group minerals (CGM) account for the majority of the current Ta production; other Ta-Nb oxides such as tapiolite, wodginite, ixiolite, rutile and pyrochlore-supergroup minerals are of minor importance. The estimated Ta resources of Africa are >50,000 tons of contained Ta₂O₅, representing 16% of the world resources. Currently, the economically most important mining districts in Africa are located within the Kibara Belt (mainly Rwanda and the DR Congo), around the Kenticha mine (Ethiopia) and in the Alto Ligonha Province (Mozambique). Production from pegmatites and related placer deposits is mostly from hundreds of artisanal and small-scale workings with only a handful of semi-industrial Ta mines. Collectively, African operations are currently responsible for more than half of the world’s primary Ta. Rare-metal granite and REP districts in Africa are part of Archaean, Palaeoproterozoic, Neoproterozoic, Palaeozoic and Mesozoic provinces. Each period of Ta ore formation is characterised by specific mineralogical and geochemical features. Compositions of CGM are variable:

In shallow-water limestones of the Plassen Formation in the Tirolic nappe of the Northern Calcareous Alps, bauxite was formed on karstified and tilted platform margin grainstones to boundstones around the ?Kimmeridgian/Tithonian boundary, or in the Early Tithonian as proven by Protopeneroplis striata Weynschenk, Labyrinthina mirabilis Weynschenk, and Salpingoporella pygmaea Gümbel. The platform established on top of the obducted ophiolite nappe stack. The onset of unroofing at the Kimmeridgian/Tithonian boundary exposed ophiolites to weathering, forming laterites, and bauxites. The weathered ophiolitic material was shed on the tilted, emerged, and karstified platform, where the bauxite accumulated. Continued subsidence led to flooding, and a Tithonian transgressive carbonate sequence sealed the bauxites. XRD analysis of the bauxite yields a composition of mainly boehmite with hematite and some berthierine, kaolinite, and chromite. SEM analysis verified magnetite, hematite, rutile, chromite, zircon, ferropseudobrookite, ilmenite, monazite, xenotime, and garnet distributed in pisoids and within the matrix. The pisoids reach a millimeter in size and partly show cores of older, larger pisoids. The composition of the chromites indicates an ophiolitic origin. Geochemical examination using major- and trace elements points to a mafic andesitic to basaltic parent material contaminated with highly fractionated rocks from an island arc. Formation of Early Tithonian bauxites in shallow-water limestones confirms Middle to Early Late Jurassic ophiolite obduction. This was followed by uplift and unroofing of the orogen from the Kimmeridgian/Tithonian boundary onwards after a period of relative tectonic quiescence with an onset of carbonate platforms during the Kimmeridgian on top of the nappe stack and the obducted Neo-Tethys ophiolites.

The present work provides an initial description of detrital platinum-group minerals (PGM) collected from alluvial sediments of rivers draining the Bushveld Complex, and from eluvial concentrations at the Onverwacht platiniferous pipe. During a field campaign, sediments were sampled at nine localities around the Bushveld Complex, and heavy mineral assemblages were investigated using optical and scanning electron microscopy (SEM) as well as microprobe analysis (EPMA) of PGM. All concentrates from the alluvial samples contain discrete PGM grains with grain sizes in the range from ~50 to 150 μm (maximum 600 μm). The overall PGM proportions are: native Pt, Pt-Pd and Pt-Fe alloys (together 54%), sperrylite (33%), cooperite/braggite (11%), and stibiopalladinite (2%). This PGM assemblage distinctly contrasts to the suite of PGM in the pristine, sulfide-bearing mineralization in the Merensky, UG-2 and Platreef, the assumed sources of the detrital PGM. Specifically, PGE-bismuthotellurides and -sulfarsenides, common in the primary ores, are missing in the assemblage of detrital PGM in the fluvial environment. Nearly all detrital PGM (98%) are Pt minerals, corroborating earlier findings that Pd-dominated PGM are unstable and are dissolved in the supergene environment, and that PGE-bismuthotellurides and -sulfarsenides, common in the PGM assemblages of the pristine ores are unstable during weathering and mechanical transport. The eluvial material collected at Onverwacht contained ca. 150 PGM grains with sizes mainly in the range 100 to 300 μm range (maximum 1.87 mm). The PGM assemblage comprises grains of Pt-Fe alloys (66%), sperrylite (14%), and many rarer PGM including stibiopalladinite, hollingworthite, laurite, PGE arsenides and PGE sulfides. The suite of eluvial PGM observed is similar to the PGM assemblage described previously from the Onverwacht pipe proper, including the type locality minerals genkinite, irarsite and platarsite, as well as some additional and possibly new PGM. Most of the relatively rare PGM detected in the suite of eluvial grains from Onverwacht were also reported in the detrital PGM assemblage from the Moopetsi river, farm Maandagshoek (Oberthür et al., 2004), indicating that many of the latter grains originate from platiniferous pipes and not from the Merensky or UG-2 reefs. Detrital PGM can be expected to be present in rivers draining PGE-bearing layered intrusions, and economic placers may form under particular sedimentological conditions. Therefore, this work also highlights the fact that the nowadays somewhat neglected field methods and basic techniques have their merits and value in mineral exploration, especially if they are combined with modern micro-analytical methods. The systematic recovery of PGM from stream sediments, soils and till should regain wider application in mineral exploration as these tools can provide useful indicators of platinum mineralization.

Growing public interest in getting information on the origin of raw materials used to manufacture goods for daily life has triggered the development of concepts to increase the transparency of raw material supply chains. Analytical proofs of origin (APOs) for raw materials may support those transparency concepts by giving evidence about the origin of a specific raw material shipment. For a variety of raw materials like gemstones, TTT (tantalum, tin, tungsten) minerals, and others, APOs have been developed. The identification of features that distinguish different origins, databases of those features from reliable reference samples, and a data evaluation strategy adopted to the envisaged application scenario are the key aspects of APO methods. Here, an overview is given on APO methods developed for different raw materials and application cases.

Cassiterite (SnO₂) has been specified as a ‘conflict mineral’ by a U.S. Government Act. This requires all companies that use tin in their products to verify that this tin does not originate from conflict regions in the Democratic Republic of the Congo where an ongoing violent conflict is fuelled by those minerals. Possible strategies to meet these requirements are based on written documents which certify the origin of the minerals. Direct chemical analyses of cassiterite, with the aim to confirm the documented sources, support those strategies in the case of doubt of the available documents. The German Federal Institute for Geosciences and Natural Resources (BGR) developed a geochemical fingerprinting method for cassiterite based on LA-ICP-MS. Single grains from cassiterite concentrates are analysed by LA-ICP-MS. Samples in question are checked against a database where data from samples of known origin are stored. The Kolmogorov–Smirnov statistic is used to demonstrate that independent samples taken from the same location show empirical cumulative distribution functions of element concentrations which are more similar to each other compared to those of samples taken from different locations. This gives confidence that cassiterite fingerprinting based on a comparison of a cassiterite sample in question with a database can be successful. The Wilcoxon rank sum test is used to establish a ‘ranking of similarity’ between a sample in question and samples from a database. This is used to assess whether the declared origin of the sample in question is credible or not.

The Tres Marias carbonate-hosted Zn-Ge deposit in Chihuahua, Mexico contains willemite [Zn₂SiO₄] with unusually high concentrations of minor and trace elements (e.g., Pb, Ge, As, P, V); Pb concentrations are as high as 2 wt %, and Ge may reach 4000 ppm (average 900 ppm). Electron microprobe analyses and synchrotron X-ray fluorescence maps show that Zn and Ge, as well as Zn and Pb are negatively correlated, whereas Ge and Pb are positively correlated across zoned willemite crystals. In cathodoluminescence (CL) images, those areas of willemite having high trace element concentrations have no, or low CL intensities, whereas zones low in trace elements (except for P) display bright blue CL colors. X-ray absorption fine structure (XAFS) spectroscopy was used to characterize the chemical nature of Ge and Pb in willemite. Comparisons to reference spectra of natural and artificial substances points to the presence of Ge⁴⁺ and Pb²⁺ in Tres Marias willemite. No evidence for Pb⁴⁺ was detected. Oscillatory zonation reflects trace element incorporation into willemite from the oxidation of primary Ge-bearing sphalerite and galena (PbS) by siliceous aqueous fluids.