The effects of lignin on mechanical, biodegradability, morphology, and thermal properties of PP/PLA/lignin were investigated. PP/PLA/lignin film were manufactured by adding PP, PLA, lignin and compatibilizer into rheomix at 200°C, at 70 rev min⁻¹ for 30 minthen pressed using Hydraulic Hot Press at 200°C–210°C, at 6 bar for 20 min. The functional groups of PP/PLA/lignin were analyzed using FTIR. The surface morphology, mechanical properties and thermal stability was measured by SEM, tensile strenght and TGA respectively. TThe FTIR intensity of vibration peak of –CH₃ cm^-1 from PP/lignin and PP/PLA/lignin at 997–993, 1458–1451 and 2966–2904 cm^-1 was lower than neat PP. The addition of lignin into PP/lignin, PLA/lignin and PP/PLA/lignin can reduce tensile strength and elongation at break. The thermal stability PP/PLA/lignin was lower than the PP/lignin but higher compared to PP/PLA biocomposites. The biodegradability of PP/PLA/lignin biocomposites was two times higher than that of PP/lignin.

The effects of metal oxide addition in polylactic acid (PLA) film were investigated in this study. PLA/Metal Oxide biocomposites were prepared by solvent casting method. The incorporation of metal oxide resulted in no chemical structure change of neat PLA. PLA/ZnO and PLA/MgO exhibited the widest inhibition while PLA/TiO₂ resulted in the smallest inhibition zone. The addition of metal oxides caused fracture and void on the surface of PLA. The addition of metal oxide into PLA films decreased the tensile strength at the concentration higher than 0.1 per hundred resin (phr). Incorporation of metal oxides accelerated the thermal degradation of PLA and tends to increase the biodegradability of PLA.